N-Methyldiethanolamine

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Names

[ CAS No. ]:
105-59-9

[ Name ]:
N-Methyldiethanolamine

[Synonym ]:
N-Methyl diethanolamine
Diethanolmethylamine
Methyldiethanolamin
MFCD00002848
Mdea (diol)
EINECS 203-312-7
Methyliminodiethanol
USAF DO-52
METHYL DIETHANLAMINE
MDEA
N-methyldiethanoloamine
N-methyl-diethanolamine
N-methyl-N,N-di(2-hydroxyethyl)amine
FC MDEA
methyl-diethanolamine
N,N-Bis(2-hydroxyethyl)methylamine
2,2'-Methyliminodiethanol
N-Methyldiethanolami
N-methyl-bis(2-hydroxyethyl)amine

Chemical & Physical Properties

[ Density]:
1.038

[ Boiling Point ]:
243 ºC

[ Melting Point ]:
-21 °C

[ Molecular Formula ]:
C5H13NO2

[ Molecular Weight ]:
119.162

[ Flash Point ]:
137 ºC

[ Exact Mass ]:
119.094627

[ PSA ]:
43.70000

[ LogP ]:
-0.72

[ Vapour density ]:
4 (vs air)

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.4675-1.4695

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
MISCIBLE

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KL7525000
CHEMICAL NAME :
Ethanol, 2,2'-(methylimino)di-
CAS REGISTRY NUMBER :
105-59-9
BEILSTEIN REFERENCE NO. :
1734441
LAST UPDATED :
199806
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C5-H13-N-O2
MOLECULAR WEIGHT :
119.19
WISWESSER LINE NOTATION :
Q2N1&2Q

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/13/1971 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4780 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
5990 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82845 No. of Facilities: 59 (estimated) No. of Industries: 5 No. of Occupations: 15 No. of Employees: 1677 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82845 No. of Facilities: 203 (estimated) No. of Industries: 5 No. of Occupations: 6 No. of Employees: 6811 (estimated) No. of Female Employees: 1031 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36

[ Safety Phrases ]:
S24

[ RIDADR ]:
2735

[ WGK Germany ]:
1

[ RTECS ]:
KL7525000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2922194000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ETHYLENE OXIDE
  • methylamine
  • 2-Methylaminoethanol
  • Bis(chloroethyl) ether
  • Formaldehyde
  • Triethanolamine
  • 2-Chloroethanol
  • Chlormethine hydrochloride
  • N-methyldiethanolamine phenylboronic ester
  • 2-(Oxazolidin-3-yl)ethanol

DownStream

  • Formaldehyde
  • methylamine
  • N'-(2-aminoethyl)-N'-methylethane-1,2-diamine
  • 2-[(2-AMINOETHYL)(METHYL)AMINO]ETHANOL
  • Chlormethine hydrochloride
  • 1-Methyl-4-phenylpiperazine
  • perfluoro-n-methylmorpholine
  • Perfluoro-[N,N-bis(fluorocarbonylmethyl)methylamine]
  • Chlormethine

Customs

[ HS Code ]: 2922194000

[ Summary ]:
2922194000 2,2'-(methylazanediyl)diethanol。supervision conditions:23(import license for dual-use item and technologies,export license for dual-use item and technologies)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

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Related Compounds

  • N-Methyldiethanolamine dipalmitate
  • N-methyldiethanolamine hydrochloride
  • N-methyldiethanolamine phenylboronic ester
  • Bis(N-methyldiethanolamine)cobalt chloride
  • 4-BROMOBENZENEBORONIC ACID N-METHYLDIETHANOLAMINEESTER
  • 4-bromobenzeneboronic acid n-methyldiethanolamine ester
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-(5-Chlorothiophen-2-yl)cyclobutan-1-amine
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • (5-Bromo-1,2,4-thiadiazol-3-yl)methanamine
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 3-Bromopyrazolo[1,5-a]pyrazin-4(5H)-one