2-fluoro-5-methoxybenzaldehyde

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Names

[ CAS No. ]:
105728-90-3

[ Name ]:
2-fluoro-5-methoxybenzaldehyde

[Synonym ]:
MFCD00070795
4-Fluoro-3-formylanisole
2-Fluoro-5-methoxybenzaldehyde
Benzaldehyde, 2-fluoro-5-methoxy-
VHR BF EO1
6-Fluoro-m-anisaldehyde
2-fluoro-5-methoxy-benzaldehyde
methyl 2-amino-3-(2-fluoro-5-hydroxyphenyl)propanoate
2-formyl-4-methoxyfluorobenzene
5-methoxy-2-fluorobenzaldehyde
6-fluoro-3-methoxybenzaldehyde

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
245.6±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H7FO2

[ Molecular Weight ]:
154.138

[ Flash Point ]:
99.4±16.7 °C

[ Exact Mass ]:
154.043015

[ PSA ]:
26.30000

[ LogP ]:
1.87

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.526

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2913000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • BENZENE, 2-(BROMOMETHYL)-1-FLUORO-4-METHOXY-
  • Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-fluoro-
  • methyl iodide
  • 1-Fluoro-4-methoxy-2-methylbenzene
  • 4-Methoxy-2-methylaniline
  • 4-fluoro-3-dibromomethylanisole
  • Formylpiperidine
  • 4-Fluorobenzyl alcohol
  • N,N-Dimethylformamide

DownStream

  • 2-Chloro-6-fluoro-3-methoxybenzaldehyde
  • 5-Methoxy-1H-indazole
  • METHYL 5-METHOXYBENZO[B]THIOPHENE-2-CARBOXYLATE
  • 2-fluoro-5-phenylmethoxybenzaldehyde
  • 2-Fluoro-5-hydroxybenzaldehyde
  • (2-Fluoro-5-methoxyphenyl)methanol
  • 9H-XANTHEN-9-ONE, 2-METHOXY-
  • 2-(2-fluoro-5-Methoxyphenyl)acetic acid
  • BENZENE, 2-(BROMOMETHYL)-1-FLUORO-4-METHOXY-

Customs

[ HS Code ]: 2913000090

[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

Articles

Xanthone natural products via N-heterocyclic carbene catalysis: total synthesis of atroviridin.

J. Org. Chem. 76(10) , 3960-7, (2011)

The total synthesis of atroviridin has been accomplished by a linear route involving the N-heterocyclic carbene (NHC)-catalyzed aroylation of the fluorobenzene derivative, Claisen cyclization of the O...

Steric effects on atropisomerism in tetraarylporphyrins. Crossley MJ, et al.

J. Am. Chem. Soc. 109(2) , 341-348, (1987)

A new synthesis of benzo [b] thiophenes utilizing an interrupted Pummerer reaction. Kobayashi K, et al.

Tetrahedron 65(12) , 2430-2435, (2009)


More Articles

Related Compounds

  • 4-Benzyloxy-2-fluoro-5-methoxybenzaldehyde
  • 2-FLUORO-3-HYDROXY-5-METHOXYBENZALDEHYDE
  • 2-Fluoro-5-trifluoromethylbenzonitrile
  • 2-FLUORO-5-METHYLBENZYLAMINE
  • 2-Fluoro-5-(pentafluorothio)benzoic acid
  • 2-Fluoro-5-bromoanisole
  • 1-(3-ethoxypropyl)-5-methyl-1H-pyrazol-3-amine
  • 2-(3-Bromoprop-1-en-2-yl)-5-(trifluoromethyl)furan
  • 1-(Azocan-2-yl)-3-methylpentan-2-one
  • 1-(4,5-Diamino-2-methylphenyl)ethanone
  • 2,2a(2)-(1,2-Ethanediyl)bis[cyclohexanol]
  • 5-Chloro-N4-phenyl-3,4-pyridinediamine
  • Methyl 2-acetyl-5-methoxy-5-methyl-4-oxohexanoate
  • Valine, N-carboxy-, N-benzyl ester, ester with 4a(2)-hydroxypropiophenone, DL-
  • Pyrrolo[3,4-c]pyrazole-4-carboxylic acid, 2,4,5,6-tetrahydro-, hydrochloride
  • (3S)-3-amino-3-(2-methyl-2H-1,2,3,4-tetrazol-5-yl)propanamide
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