Oxydiethylene bis(chloroformate)

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Names

[ CAS No. ]:
106-75-2

[ Name ]:
Oxydiethylene bis(chloroformate)

[Synonym ]:
diethylene glycol bischloroformate
2,2'-oxydiethanol bischloroformate
bis(ethyl 2-chloroformate)ether
Diglycol chloroformate
oxydiethane-2,1-diyl dichlorocarbonate
Diethylene glycol chloroformate
MFCD00018800
2,2'-oxydiethyl chloroformate
Diglykol-bis(chlorameisensaeureester)
Carbonochloridic acid,oxydi-2,1-ethanediyl ester
bis-(2-chlorocarbonyloxy-ethyl) ether
Oxydiethylene bis(chloroformate)
Diglycol chlorformate
EINECS 203-430-9
Oxydiethylene chloroformate

Chemical & Physical Properties

[ Density]:
1.48

[ Boiling Point ]:
280ºC at 760 mmHg

[ Molecular Formula ]:
C6H8Cl2O5

[ Molecular Weight ]:
231.03100

[ Flash Point ]:
118.2ºC

[ Exact Mass ]:
229.97500

[ PSA ]:
61.83000

[ LogP ]:
1.75380

[ Index of Refraction ]:
1.504

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ6700000
CHEMICAL NAME :
Formic acid, chloro-, oxydiethylene ester
CAS REGISTRY NUMBER :
106-75-2
BEILSTEIN REFERENCE NO. :
1812829
LAST UPDATED :
199806
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C6-H8-Cl2-O5
MOLECULAR WEIGHT :
231.04
WISWESSER LINE NOTATION :
GVO2O2OVG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
813 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
169 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978

Safety Information

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16-S26-S27-S45-S61-S23

[ RIDADR ]:
2742

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • phosgene
  • Diethylene glycol

DownStream

  • Bis(chloroethyl) ether
  • Diethylene glycol
  • Diallyl oxydi-2,1-ethanediyl biscarbonate
  • 3,5,8,11,13-Pentaoxapentadecanedioicacid, 2,14-dimethyl-4,12-dioxo-, 1,15-bis[2-(2-chloroethoxy)ethyl] ester
  • 2,5,8,10-Tetraoxatridecanoicacid, 9-oxo-, propyl ester
  • 2-(2-ethoxycarbonyloxyethoxy)ethyl ethyl carbonate
  • hexyl 2-[2-[2-(1-hexoxycarbonylethoxycarbonyloxy)ethoxy]ethoxycarbonyloxy]propanoate
  • 2-methylpropyl 2-[2-[2-(2-methylpropoxycarbonylmethoxycarbonyloxy)ethoxy]ethoxycarbonyloxy]acetate
  • 5,8,11-Trioxa-2,3,13,14-tetraazapentadecanedioicacid, 4,12-dioxo-, diethyl ester (9CI)
  • Carbamic acid,(1-methylethyl)-, oxydi-2,1-ethanediyl ester (9CI)

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • oxydiethylene bis[(3-isocyanatomethylphenyl)carbamate]
  • oxydiethylene bis(2-ethylhexanoate)
  • oxydiethylene bis[[[1,3,3-trimethyl-5-[[(2-methyl-6-oxo-1-piperidyl)carbonyl]amino]cyclohexyl]methyl]carbamate]
  • (oxydiethylene)bis[bis(2-hydroxyethyl)sulphonium] bis(toluene-p-sulphonate)
  • oxydiethylene bis[[(5-isocyanato-1,3,3-trimethylcyclohexyl)methyl]carbamate]
  • hexamethylene bis(chloroformate)
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine