allyl bromide

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Names

[ CAS No. ]:
106-95-6

[ Name ]:
allyl bromide

[Synonym ]:
3-Bromo-1-propene
1-bromo-2-propene
bromo-3propene
prop-2-enyl bromide
Allylbromid
3-bromo-propen
allylic bromide
allylbromide
CH2=CHCH2Br
Bromoallylene
3-Bromopropylene
3-Brompropen
1-Propene, 3-bromo-
allyl bromide
2-propenyl bromide
ALLYLBROMID-R
MFCD00000244
3-bromoprop-1-ene
EINECS 203-446-6
BROMALLYLENE
3-Bromopropene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
68.1±9.0 °C at 760 mmHg

[ Melting Point ]:
-119 °C

[ Molecular Formula ]:
C₃H₅Br

[ Molecular Weight ]:
120.976

[ Flash Point ]:
-2.2±0.0 °C

[ Exact Mass ]:
119.957458

[ LogP ]:
1.79

[ Vapour density ]:
4.2 (vs air)

[ Vapour Pressure ]:
153.5±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.455

[ Stability ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC7090000

CHEMICAL NAME :: Propene, 3-bromo-

CAS REGISTRY NUMBER :: 106-95-6

BEILSTEIN REFERENCE NO. :: 0605308

LAST UPDATED :: 199712

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C3-H5-Br

MOLECULAR WEIGHT :: 120.99

WISWESSER LINE NOTATION :: E2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 120 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 gm/m3/30M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 48 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 4110 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Unscheduled DNA synthesis

TEST SYSTEM :: Human HeLa cell

DOSE/DURATION :: 500 umol/L

REFERENCE :: CALEDQ Cancer Letters (Shannon, Ireland). (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1975- Volume(issue)/page/year: 20,263,1983

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H301-H314-H340-H350-H400

[ Precautionary Statements ]:
P201-P210-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R23/25;R34;R50

[ Safety Phrases ]:
S16-S26-S36/37/39-S45-S60-S61

[ RIDADR ]:
UN 1099 3/PG 1

[ WGK Germany ]:
2

[ RTECS ]:
UC7090000

[ Packaging Group ]:
I

[ Hazard Class ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Allyl alcohol
ALLYL CHLORIDE
1,3-Dibromopropane
Trimethyl Allyloxysilane
2,6-lutidine
1,3-dibromo-2-(tert-butylsulfonyl)-propane
allylbromobis(4-methoxyphenyl)-l4-tellane
3-Thiophenecarboxaldehyde
Benzyl bromide
4-Methoxybenzaldehyde

DownStream

N,N-bis(prop-2-enyl)propan-2-amine
DIMETHYL 2-ALLYL-2-(PROP-2-YN-1-YL)MALONATE
4-hydroxy-1-prop-2-enylindole-3-carbaldehyde
N-benzyl-6-methylhepta-1,5-dien-4-amine
4-prop-2-enoxybut-2-en-1-ol
1,4-bis(allyloxy)-cis-2-butene
Methyl 2-((tert-butoxycarbonyl)amino)pent-4-enoate
Allyl salicylate
1-but-3-enyl-4-nitrobenzene
2,3,3-trimethyl-1-prop-2-enylindol-1-ium,bromide

Customs

[ HS Code ]: 2903399090

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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