2-(Trimethylsilyl)ethanesulfonyl chloride

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Names

[ Name ]:
2-(Trimethylsilyl)ethanesulfonyl chloride

[Synonym ]:
SES-Cl
Ethanesulfonyl chloride, 2-(trimethylsilyl)-
2-Trimethylsilylethylsulfonyl chloride
2-(Trimethylsilyl)ethanesulfonyl chloride
Me3SiCH2CH2SO2Cl
2-trimethylsilanyl-ethanesulfonyl chloride

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
209.4±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₁₃ClO₂SSi

[ Molecular Weight ]:
200.759

[ Flash Point ]:
80.5±22.6 °C

[ Exact Mass ]:
200.009399

[ PSA ]:
42.52000

[ LogP ]:
2.32

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.444

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
26

[ RIDADR ]:
UN 1993 3/PG 2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Sodium 2-(trimethylsilyl)ethanesulfonate
2-(trimethylsilyl)ethanesulfonic acid
Vinyltrimethylsilane

DownStream

N,N-bis(3-cyanopropyl)-2-trimethylsilylethanesulfonamide
N,N-bis(4-cyanobutyl)-2-trimethylsilylethanesulfonamide
N,N-bis(5-cyanopentyl)-2-trimethylsilylethanesulfonamide
N,N-bis(4-aminobutyl)-2-trimethylsilylethanesulfonamide
N,N-bis(5-aminopentyl)-2-trimethylsilylethanesulfonamide
N,N-bis(6-aminohexyl)-2-trimethylsilylethanesulfonamide
2-[[1,9-bis(2-trimethylsilylethylsulfonyl)-1,5,9-triazacyclotetradec-5-yl]sulfonyl]ethyl-trimethylsilane

Articles

2-(Trimethylsilyl)ethanesulfonyl (or SES) group in amine protection and activation.

Chem. Rev. 106 , 2249, (2006)

N-(2-(trimethylsilyl)ethanesulfonyl)-2-phenylaziridine
1,6,11-tris-(2-(trimethylsilyl)ethanesulfonyl)-1,6,11-triazacyclopentadecane [4,4,4]
1,5,10-tris-(2-(trimethylsilyl)ethanesulfonyl)-1,5,10-triazacyclotetradecane [4,4,3]
1,8,15-tris-2-(trimethylsilyl)ethanesulfonyl-1,8,15-triazapentadecane
1,5,10-tris-2-(trimethylsilyl)ethanesulfonyl-1,5,10-triazadecane
1,6,11-tris-2-(trimethylsilyl)ethanesulfonyl-1,6,11-triazaundecane
Ethyl 2-[5-methyl-2-(methylamino)-1,3-thiazol-4-yl]acetate
rac-(1R,3S)-2,2-dimethyl-3-(1-sulfanylethyl)cyclobutane-1-carboxylic acid
(4-Chloro-3-nitrophenyl)methanethiol
8-Bromo-2,3,4,5-tetrahydro-1-benzoxepine-5-thiol
6-fluoro-4-sulfanyl-3,4-dihydro-2H-1lambda6-benzothiopyran-1,1-dione
1-(1-Ethylpiperidin-4-yl)ethane-1-thiol
Ethyl 3-(4-chlorophenyl)-1-(iodomethyl)-2-oxabicyclo[2.1.1]hexane-4-carboxylate
Ethyl 1-(iodomethyl)-3-(6-(trifluoromethyl)pyridin-3-yl)-2-oxabicyclo[2.1.1]hexane-4-carboxylate
Ethyl 1-(iodomethyl)-3-(4-methanesulfonylphenyl)-2-oxabicyclo[2.1.1]hexane-4-carboxylate
1-(1-Benzothiophen-5-yl)-2-(methylamino)propan-1-one hydrochloride

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