1,1,1-TRIS(CHLOROMETHYL)ETHANE

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Names

[ CAS No. ]:
1067-09-0

[ Name ]:
1,1,1-TRIS(CHLOROMETHYL)ETHANE

[Synonym ]:
1-chloro-2,2-dichloromethylpropane
1,3-dichloro-2-chloromethyl-2-methylpropane
MFCD00013686

Chemical & Physical Properties

[ Density]:
1.271 g/mL at 25ºC(lit.)

[ Boiling Point ]:
85ºC (14 torr)

[ Melting Point ]:
18-87ºC

[ Molecular Formula ]:
C₅H₉Cl₃

[ Molecular Weight ]:
175.48400

[ Flash Point ]:
187 °F

[ Exact Mass ]:
173.97700

[ LogP ]:
2.70910

[ Vapour Pressure ]:
0.568mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.482(lit.)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-27-36/37/39

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2903199000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,1,1-tris(hydroxymethyl)ethane
diazomethane
Chloroform
(2-(METHYLSULFONYL)PHENYL)METHANAMINE
methanediyl

DownStream

1,1,1-tris(diphenylphosphinomethyl)ethane
4-methyl-1-phenylpent-4-en-1-one
4-Pentenoic acid

Customs

[ HS Code ]: 2903199000

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Photochemical Reactions of Diazomethane with Polyhalomethanes and a-Haloesters1. Urry WH and Eiszner JR.

J. Am. Chem. Soc. 74(23) , 5822-26, (1952)

1,1,1-TRIS(CHLOROMETHYL)PROPANE
1,1,1-TRIS(MERCAPTOMETHYL)ETHANE
1,1,1-tris(dimethylphosphinomethyl)ethane
(1,1,1-tris(diphenylphosphinomethyl)ethane)Ir(H)3
1,1,1-tris(ethylsulfanyl)ethane
1,1,1-tris(diphenylphosphinomethyl)ethane
4-(2,2,2-trifluoroethyl)-4H,5H,6H,7H-thieno[3,2-c]pyridine
7-{bicyclo[4.1.0]heptan-3-yl}-4H,5H,6H,7H-furo[2,3-c]pyridine
N-(propan-2-yl)-octahydroindolizin-2-amine
4-{bicyclo[3.1.0]hexan-3-yl}-4H,5H,6H,7H-furo[3,2-c]pyridine
4-(2-methylcyclopropyl)-3H,4H,5H,6H,7H-imidazo[4,5-c]pyridine
4-(3-methoxycyclobutyl)-4H,5H,6H,7H-furo[3,2-c]pyridine
Ethyl({[5-(trifluoromethyl)pyridin-3-yl]methyl})amine
(2-Methylpropyl)({[5-(trifluoromethyl)pyridin-3-yl]methyl})amine
(propan-2-yl)({[2-(1H-pyrrol-1-yl)phenyl]methyl})amine
[1-(3,5-Dichlorophenyl)-2-phenylethyl](propan-2-yl)amine

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