AMMONIUM O,O-DIETHYLDITHIOPHOSPHATE

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Names

[ CAS No. ]:
1068-22-0

[ Name ]:
AMMONIUM O,O-DIETHYLDITHIOPHOSPHATE

[Synonym ]:
ammonium O,O-diethyl phosphorodithioate
MFCD00012635
EINECS 213-942-4
AMMONIUM O,O-DIETHYLDITHIOPHOSPHATE
Ammonium O,O-Diethyldithiophosphate, Typically
O,O-Diethyl hydrogen dithiophosphate ammonium salt

Chemical & Physical Properties

[ Density]:
1.214g/cm3

[ Boiling Point ]:
232.7ºC at 760mmHg

[ Melting Point ]:
164-166 °C(lit.)

[ Molecular Formula ]:
C4H14NO2PS2

[ Molecular Weight ]:
203.26300

[ Flash Point ]:
94.5ºC

[ Exact Mass ]:
203.02000

[ PSA ]:
102.40000

[ LogP ]:
3.18820

[ Appearance of Characters ]:
Crystalline

[ Vapour Pressure ]:
0.0153mmHg at 25°C

[ Index of Refraction ]:
1.546

[ Storage condition ]:
?20°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BP8145000
CHEMICAL NAME :
Ammonium, O,O-diethyl phosphorodithioate
CAS REGISTRY NUMBER :
1068-22-0
LAST UPDATED :
199106
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C4-H11-O2-P-S2.H3-N
MOLECULAR WEIGHT :
203.28
WISWESSER LINE NOTATION :
SHPS&O2&O2 &ZH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7900 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
10 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,109,1990

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
20/21/22

[ Safety Phrases ]:
S36

[ RIDADR ]:
UN 3335

[ WGK Germany ]:
3

[ RTECS ]:
BP8145000

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Diethyl dithiophosphoric acid
  • Ethanol
  • mixed thioanhydride of O,O-diethyl hydrogen phosphorodithioate and ethylphenylphosphinothious acid
  • Ethanethiol

DownStream

  • S-(Chlormethyl)-O,O-diethyldithiophosphat
  • ethion
  • Dithiophosphoric acid O,O-diethyl S-(4-nitrobenzyl) ester
  • diethoxy-[(3-methyl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-sulfanylidene-λ5-phosphane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Simple hollow fiber renewal liquid membrane extraction method for pre-concentration of Cd(II) in environmental samples and detection by flame atomic absorption spectrometry.

Anal. Chim. Acta 638(1) , 45-50, (2009)

A hollow fiber renewal liquid membrane (HFRLM) extraction method to determine cadmium (II) in water samples using Flame Atomic Absorption Spectrometry (FAAS) was developed. Ammonium O,O-diethyl dithio...

Effects of some chelating agents on the uptake and distribution of 203Hg2+ in the brown trout (Salmo trutta): studies on ethyl- and isopropylxanthate, diethyl- and diisopropyldithiophosphate, dimethyl- and diethyldithiocarbamate and pyridinethione.

Arch. Toxicol. 62(5) , 387-91, (1988)

Brown trout, Salmo trutta, were exposed to water containing 0.1 microgram/l 203Hg2+, alone or with potassium ethylxanthate (PEX), sodium isopropylxanthate (SIX), sodium diethyldithiophosphate (SEP), s...

Thermospray flame furnace-AAS determination of copper after on-line sorbent preconcentration using a system optimized by experimental designs.

Anal. Sci. 21(11) , 1337-42, (2005)

The present paper describes the on-line coupling of a flow-injection system to a new technique, thermospray flame furnace-AAS (TS-FF-AAS), for the preconcentration and determination of copper in water...


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Related Compounds

  • ammonium O,O-diphenyl dithiophosphate
  • ammonium O,O-dimethyl thiophosphate
  • AMMONIUM O,O-DIISOPROPYLTHIOPHOSPHATE
  • ammonium O,O-bis(methylphenyl) dithiophosphate
  • ammonium O,O-bis(dimethylphenyl) dithiophosphate
  • Ammonium O,O-dimethyl dithiophosphate
  • 4-[[4-[[2-(1H-Indol-3-yl)ethyl]amino]phenyl]amino]-2-pyridinemethanol
  • 1,4-Dimethyl-2,5-dinitrosobenzene
  • 4-chloro-2-ethyl-5-methoxy-2H-pyridazin-3-one
  • 3,4-Quinolinediamine, 6-methoxy-
  • 7-Methoxyquinoline-3,4-diamine
  • 2-(Ethenyloxy)ethyl 2-propanesulfonate
  • 7-(tert-Butyl)indolin-2-one
  • diethyl N-cyanocarbonimidate
  • 2-(5-Phenyl-1,2,4-oxadiazol-3-yl)ethanol
  • 2-(3-Fluoropyridin-2-yl)propan-2-ol
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