ISOPROPYLMAGNESIUM CHLORIDE

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Names

[ CAS No. ]:
1068-55-9

[ Name ]:
ISOPROPYLMAGNESIUM CHLORIDE

[Synonym ]:
EINECS 213-947-1
magnesium,propane,chloride
MFCD00000466
IsopropylMagnesiuM Chloride

Chemical & Physical Properties

[ Density]:
0.98 g/mL at 20 °C

[ Boiling Point ]:
256 °C

[ Molecular Formula ]:
C3H7ClMg

[ Molecular Weight ]:
102.84600

[ Flash Point ]:
72 °F

[ Exact Mass ]:
102.00900

[ LogP ]:
2.05350

[ Storage condition ]:
Flammables + water-Freezer (-20°C)e area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H261-H314-H335-H351

[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235

[ Hazard Codes ]:
F+: Highly flammable;C: Corrosive;

[ Risk Phrases ]:
R12;R14/15;R19;R22;R34;R66;R67

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S16-S33

[ RIDADR ]:
UN 3399 4.3/PG 2

[ WGK Germany ]:
1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Chloropropane
  • Dimethyl (1-diazo-2-oxopropyl)phosphonate
  • Magnesium

DownStream

  • 2-Isopropylnaphthalene
  • 2-methyl-1-naphthalen-2-ylpropan-1-one
  • N,N-diethyl-2-methyl-1-tributylstannylpropan-1-amine
  • 3-propan-2-ylcycloheptan-1-one
  • 2-Methyl-3-pentanone
  • (S)-(-)-2-ISOCYANATOGLUTARICACIDDIETHYLESTER
  • Benzyl alcohol
  • Benzenemethanol, α-(1-methylethyl)-, (αR)-
  • 2,6-diformylpyridine
  • 6-Brompyridin-2-carbaldehyd

Articles

Direct, catalytic, and regioselective synthesis of 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles from N-oxides.

Org. Lett. 16(3) , 864-7, (2014)

A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of cop...


More Articles

Related Compounds

  • Isopropylmagnesium Chloride
  • ISOPROPYLMAGNESIUM CHLORIDE-LITHIUM CHLORIDE
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  • Tetrabutylphosphonium chloride
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