Acethydrazide

Suppliers

Names

[ Name ]:
Acethydrazide

[Synonym ]:
Methylformylhydrazine
1-Methylformylhydrazine
EINECS 213-948-7
acetylhydrazine
Acetyl Hydrazide
Acetic acid hydrazide Acetylhydrazine
MFCD00007610
Acetohydrazide(2)
Acetic acid, hydrazide
Acetohydrazide
ACETIC HYDRAZIDE
Acethydrazide
Acetic acid hydrazide

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
246.0±9.0 °C at 760 mmHg

[ Melting Point ]:
58-68 °C(lit.)

[ Molecular Formula ]:
C₂H₆N₂O

[ Molecular Weight ]:
74.082

[ Flash Point ]:
102.6±18.7 °C

[ Exact Mass ]:
74.048012

[ PSA ]:
55.12000

[ LogP ]:
-1.64

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.432

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
soluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AI1225000

CHEMICAL NAME :: Acetic acid, hydrazide

CAS REGISTRY NUMBER :: 1068-57-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C2-H6-N2-O

MOLECULAR WEIGHT :: 74.10

WISWESSER LINE NOTATION :: ZMV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 153 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 116 mg/kg

TOXIC EFFECTS :: Endocrine - hypoglycemia

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - wild bird species

DOSE/DURATION :: 42200 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: Micronucleus test

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 150 mg/kg

REFERENCE :: IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 19,939,1981

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H319-H341-H351

[ Precautionary Statements ]:
P281-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1759

[ WGK Germany ]:
1

[ RTECS ]:
AI1225000

[ Packaging Group ]:
II

[ HS Code ]:
2928000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

ethyl acetate
Ethyl acetimidate hydrochloride
Ethanoic anhydride
Hydrazinecarboxylic acid, 2-acetyl-, 1,1-dimethylethyl ester (9CI)
ethyl 2-acetylacetoacetate
Acetamide,N-(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)-
acetic acid
Methyl acetate
triacetylmethane
2-acetyl-1,3-diphenyl-1,3-propanedione

DownStream

1-methyl-4,5-dihydro-[1,2,4]triazolo[3,4-d][1,5]benzothiazepine
5-METHYL-[1,3,4]OXADIAZOLE-2-THIOL
2-methyl-1,3,4-oxadiazole
N'-Acetylacetohydrazide
1-acetylethoxycarbonylformamidrazone
diethyl 1H-1,2,4-triazole-3,5-dicarboxylate
9-fluoro-6-(4-fluorophenyl)-1-methyl-5,6-dihydro-4H-[1,2,4]triazolo[4,3-a][1]benzazepine
5-methyl-1,3,4-oxadiazol-2-ylamine
3H-1,2,4-Triazole-3-thione,2,4-dihydro-4,5-dimethyl-

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

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