1H-Imidazole-4-carboxylic acid

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Names

[ CAS No. ]:
1072-84-0

[ Name ]:
1H-Imidazole-4-carboxylic acid

[Synonym ]:
4-IMidazolecarboxylic Acid
IMIDAZOLE-4-CARBOXYLIC ACID
1H-imidazol-4-ylcarboxylic acid
MFCD00082203
1H-Imidazole-5-carboxylic acid
4,5-imidazoledicarboxylic acid
Imidazol-4-carboxylic acid
RARECHEM AL BE 0762
4-hydroxy imizodale
4-carboxyimidazole
1H-Imidazole-4-carboxylic acid
EINECS 214-017-8

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
495.0±18.0 °C at 760 mmHg

[ Melting Point ]:
294-295 °C(lit.)

[ Molecular Formula ]:
C4H4N2O2

[ Molecular Weight ]:
112.09

[ Flash Point ]:
253.2±21.2 °C

[ Exact Mass ]:
112.027275

[ PSA ]:
65.98000

[ LogP ]:
0.46

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

[ Index of Refraction ]:
1.617

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NI4001000
CHEMICAL NAME :
Imidazole-4-carboxylic acid
CAS REGISTRY NUMBER :
1072-84-0
LAST UPDATED :
198709
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C4-H4-N2-O2
MOLECULAR WEIGHT :
112.10
WISWESSER LINE NOTATION :
T5M CNJ DVQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBPHAW Progress in Biochemical Pharmacology. (S. Karger AG, Postfach CH-4009 Basel, Switzerland) V.1- 1965- Volume(issue)/page/year: 1,542,1965

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
NI4001000

[ HS Code ]:
2933290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Imidazolemethanol
  • 4-Bromoimidazole
  • Formyl acetate
  • Imidazole
  • 4,5-Imidazoledicarboxylic acid
  • 1H-Imidazole-5-carboxamide,N-phenyl-
  • trans-Urocanic acid

DownStream

  • 4-Nitro-1H-imidazole-5-carboxylic acid
  • 1H-Imidazole-4-carboxylicacid, 5-nitro-, methyl ester
  • Imidazole
  • 4-Imidazolemethanol
  • 5H,10H-DIIMIDAZO[1,5-A:1',5'-D]PYRAZINE-5,10-DIONE
  • 2,4,5-Triiodoimidazole
  • Methyl 4-imidazolecarboxylate
  • Ethyl imidazole-4-carboxylate
  • 1-Trityl-1H-imidazole-4-carboxylic acid

Customs

[ HS Code ]: 2933290090

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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Phosphate ester hydrolysis by hydroxo complexes of trivalent lanthanides stabilized by 4-imidazolecarboxylate.

Inorg. Chem. 45(23) , 9502-17, (2006)

The anion of 4-imidazolecarboxylic acid (HL) stabilizes hydroxo complexes of trivalent lanthanides of the type ML(OH)+ (M = La, Pr) and M2L(n)(OH)(6-n) (M = La, n = 2; M = Pr, n = 2, 3; M = Nd, Eu, Dy...


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Related Compounds

  • 1-Tosyl-1H-imidazole-4-carboxylic acid
  • 5-bromo-1H-imidazole-4-carboxylic acid
  • 2-AMINO-1H-IMIDAZOLE-4-CARBOXYLIC ACID
  • 2-ETHYL-1H-IMIDAZOLE-4-CARBOXYLIC ACID
  • 1-Ethyl-1H-imidazole-4-carboxylic acid
  • 5-AMINO-1H-IMIDAZOLE-4-CARBOXYLIC ACID
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  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-(1H-imidazol-5-yl)-5-(trifluoromethyl)-1,2-oxazole-4-carboxylic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
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  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-Bromo-2-(2,2-difluoro-1-hydroxyethyl)phenol