2-amino-5-bromopyridine

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Names

[ Name ]:
2-amino-5-bromopyridine

[Synonym ]:
2-Pyridinamine, 5-bromo-
5-bromo-2-aminopyridine
2-Amino-5-bromopyridine
AMINO-5-BROMOPYRIDINE
5-bromo-2-pyridylamine
2-Amino-5-bromopyrid
5-bromopyridin-2-yl amine
5-bromopyridin-2-amine
5-Bromo-2-pyridinamine
EINECS 214-019-9
2-amino-5-bromo-pyridine
MFCD00006323

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
230.9±20.0 °C at 760 mmHg

[ Melting Point ]:
133-138 °C(lit.)

[ Molecular Formula ]:
C₅H₅BrN₂

[ Molecular Weight ]:
173.011

[ Flash Point ]:
93.4±21.8 °C

[ Exact Mass ]:
171.963608

[ PSA ]:
38.91000

[ LogP ]:
1.98

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.636

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H319-H335

[ Precautionary Statements ]:
P261-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
2

[ HS Code ]:
29333999

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Aminopyridine
5-bromo-2-(dibenzylamino)pyridine
5-bromo-N,N-bis[(4-methoxyphenyl)methyl]pyridin-2-amine
5-Bromo-2-nitropyridine
pyridinium N-[2'-(5'-bromopyridyl)]aminide
2(1H)-Pyridinimine, 5-bromo-1-(difluoromethyl)
N-(5-bromopyridin-2-yl)nitramide
N'-(5-Bromopyridin-2-yl)-N,N-dimethylformimidamide

DownStream

N'-(5-Bromo-2-pyridinyl)-N,N-dimethyl-1,2-ethanediamine
4-(dimethylamino)-3-imidazo[1,2-a]pyridin-6-ylbut-3-en-2-one
2-Amino-5-phenylpyridine
Biphenyl
5-p-tolylpyridin-2-ylamine
5-Bromo-3-iodopyridin-2-amine
6-Bromo-[1,2,4]triazolo[1,5-a]pyridine
5-Bromo-3-chloro-2-pyridinamine
3,5-dibromopyridin-2-amine
6-Bromo-2-methylimidazo[1,2-a]pyridine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

2-Amino-5-bromo-pyridinium 3-amino-benzoate.

Acta Crystallogr. Sect. E Struct. Rep. Online 66(Pt 3) , o664, (2010)

In the title salt, C(5)H(6)BrN(2) (+)·C(7)H(6)NO(2) (-), the pyridine N atom of the 2-amino-5-bromo-pyridine mol-ecule is protonated. In the crystal, the protonated N atom and the 2-amino group are hy...

2-Amino-5-bromo-pyridine-benzoic acid (1/1).

Acta Crystallogr. Sect. E Struct. Rep. Online 66(Pt 3) , o663, (2010)

In the title adduct, C(5)H(5)BrN(2)·C(7)H(6)O(2), the carboxyl group of the benzoic acid mol-ecule is twisted away from the attached ring by 12.97 (11)°. The 2-amino-5-bromo-pyridine mol-ecules inter-...

Structural analysis of oligosaccharides by a combination of electrospray mass spectrometry and bromine isotope tagging of reducing-end sugars with 2-amino-5-bromopyridine.

Rapid Commun. Mass Spectrom. 17(13) , 1462-6, (2003)

Model reducing-end oligosaccharides were successfully labeled by a brominated aromatic amine reagent, 2-amino-5-bromopyridine (ABP), through reductive amination. Using either a combination of liquid c...