Succinic anhydride

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Names

[ CAS No. ]:
108-30-5

[ Name ]:
Succinic anhydride

[Synonym ]:
SAN
3,4-dihydrofuran-2,5-dione
succinylanhydride
Dihydrofuran-2,5-dione
dihydro-furan-2.5-dione
succinic acid anhydride
tetrahydrofuran-2,5-dione
Oxolan-2,5-dione
SAA
Succinic Anhydride
SUCCINYL OXIDE
2,5-Diketotetrahydrofuran
dihydrothran-2,5-dione
MFCD00005525
dihydro-2,5-furandione
EINECS 203-570-0

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
261.0±0.0 °C at 760 mmHg

[ Melting Point ]:
118-120 °C(lit.)

[ Molecular Formula ]:
C4H4O3

[ Molecular Weight ]:
100.073

[ Flash Point ]:
122.1±15.9 °C

[ Exact Mass ]:
100.016045

[ PSA ]:
43.37000

[ LogP ]:
-1.30

[ Vapour density ]:
3.5 (vs air)

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.470

[ Storage condition ]:
Store at 0-5°C

[ Stability ]:
Stable. Incompatible with oxidising agents, strong acids, strong bases, alcohols, amines. Avoid exposure to water or moisture.

[ Water Solubility ]:
<0.1 g/100 mL at 21 ºC (decomposes)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WN0875000
CHEMICAL NAME :
Succinic anhydride
CAS REGISTRY NUMBER :
108-30-5
BEILSTEIN REFERENCE NO. :
0108441
LAST UPDATED :
199710
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
C4-H4-O3
MOLECULAR WEIGHT :
100.08
WISWESSER LINE NOTATION :
T5VOVTJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1510 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
13 gm/kg/13W-I
TOXIC EFFECTS :
Liver - changes in liver weight Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2618 mg/kg/20D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10500 mg/kg/16D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
19500 mg/kg/13W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2600 mg/kg/65W-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
79 mg/kg
SEX/DURATION :
female 8-10 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - other developmental abnormalities

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - hamster Embryo
DOSE/DURATION :
100 ug/L
REFERENCE :
IJCNAW International Journal of Cancer. (International Union Against Cancer, 3 rue du Conseil- General, 1205 Geneva, Switzerland) V.1- 1966- Volume(issue)/page/year: 19,642,1977 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 15,265,1977 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 15,265,1977 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4008 No. of Facilities: 263 (estimated) No. of Industries: 7 No. of Occupations: 5 No. of Employees: 3059 (estimated) No. of Female Employees: 1207 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314-H317-H334-H335

[ Precautionary Statements ]:
P260-P280-P284-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37

[ Safety Phrases ]:
S25

[ RIDADR ]:
UN 3261 8 / PGII

[ WGK Germany ]:
1

[ RTECS ]:
WN0875000

[ HS Code ]:
2932999099

Synthetic Route

Precursor & DownStream

Precursor

  • carbon monoxide
  • epoxypropane
  • Maleic anhydride
  • ETHYLENE OXIDE
  • Succinic acid
  • SUCCINYL CHLORIDE
  • Diethylenetriamine
  • β-Propiolactone
  • Maleic acid
  • n-Butane

DownStream

  • 4-(benzoyldioxy)-4-oxobutyric acid
  • Benzenebutanoic acid,2,5-dimethoxy-
  • 4-oxo-4-tetradecoxybutanoate
  • N-(3-CARBAMOYL-4,5-DIMETHYL-THIOPHEN-2-YL)-SUCCINAMIC ACID
  • 4-oxo-4-(2-phenylethylamino)butanoic acid
  • (R)-(+)-PROPYLENEOXIDE
  • 1,2-dipalmitoyl-3-succinylglycerol
  • 1,2,5-Oxadiazole,3,4-dimethyl-
  • Succinohydrazide
  • 4-(4-bromophenyl)butanoic acid

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • succinic anhydride
  • Succinic anhydride
  • succinic anhydride-d4
  • 13C4-succinic anhydride
  • ethylsuccinic anhydride
  • ethylsuccinic anhydride
  • N-[2-(1,2,3,4-tetrahydroquinolin-6-yl)ethyl]cyclopropanecarboxamide
  • 2,3-dimethyl-N-[2-(1,2,3,4-tetrahydroquinolin-6-yl)ethyl]butanamide
  • 1-[6-(2-Aminoethyl)-1,2,3,4-tetrahydroquinolin-1-yl]-2-(dimethylamino)ethan-1-one
  • 3-Propyl-1-[2-(1,2,3,4-tetrahydroquinolin-6-yl)ethyl]urea
  • 3-(2-Methylpropyl)-1-[2-(1,2,3,4-tetrahydroquinolin-6-yl)ethyl]urea
  • 6-(2-aminoethyl)-N-tert-butyl-1,2,3,4-tetrahydroquinoline-1-carboxamide
  • 6-(2-aminoethyl)-N-ethyl-1,2,3,4-tetrahydroquinoline-1-carboxamide
  • 2-[1-(Butane-1-sulfonyl)-1,2,3,4-tetrahydroquinolin-6-yl]ethan-1-amine
  • 7-Fluoro-2-(oxan-4-yl)quinolin-3-ol
  • 7-Fluoro-2-(oxan-3-yl)quinolin-3-ol
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