2,4-Lutidine

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Names

[ CAS No. ]:
108-47-4

[ Name ]:
2,4-Lutidine

[Synonym ]:
2,4-Dimethylpyridine
Lutidine
EINECS 203-586-8
MFCD00006337
Pyridine, 2,4-dimethyl-

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
157.4±9.0 °C at 760 mmHg

[ Melting Point ]:
-60 °C

[ Molecular Formula ]:
C7H9N

[ Molecular Weight ]:
107.153

[ Flash Point ]:
37.2±0.0 °C

[ Exact Mass ]:
107.073502

[ PSA ]:
12.89000

[ LogP ]:
1.65

[ Vapour Pressure ]:
3.6±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.502

[ Water Solubility ]:
15 g/100 mL (20 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OK9400000
CHEMICAL NAME :
2,4-Lutidine
CAS REGISTRY NUMBER :
108-47-4
BEILSTEIN REFERENCE NO. :
0001506
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C7-H9-N
MOLECULAR WEIGHT :
107.17

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sex chromosome loss and nondisjunction
TEST SYSTEM :
Yeast - Saccharomyces cerevisiae
DOSE/DURATION :
5000 ppm
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 163,23,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6633 No. of Facilities: 10 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 120 (estimated) No. of Female Employees: 120 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301 + H311 + H331-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310 + P330-P302 + P352 + P312-P304 + P340 + P312-P370 + P378

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R10;R20/21;R25;R36/37/38

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 1992 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
OK9400000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Acetonitrile
  • isoprene
  • Diethyl 2,4-pyridinedicarboxylate
  • 2,4-Dimethyl-5-nitropyridine
  • 2,4-Dimethyl-3-nitropyridine
  • Formaldehyde
  • Acetone
  • Acetylene
  • DIMETHYL(VINYL)ETHYNYLCARBINOL
  • 3-Toluidine

DownStream

  • 2,4-DIMETHYL-PYRIDINE 1-OXIDE
  • 2-Chloromethyl-4-methylpyridine
  • 4-methyl-2-(trichloromethyl)pyridine
  • 7-Methyl-1H-pyrrolo[3,2-b]pyridine
  • 1,1-DIMETHYLUREA
  • s-Triazine, 2,4,6-triphenyl- (8CI)
  • methyl-4 phenyl-7 6H naphtyridin-1,6 one-5
  • 6-(1,3-dioxolan-2-yl)-4-methylpyridin-3-amine
  • Lutidinic acid

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

[Plasmids for biodegradation of 2,6-dimethylpyridine, 2,4-dimethylpyridine, and pyridine in strains of Arthrobacter].

Mol. Gen. Mikrobiol. Virusol. (5-6) , 10-3, (1992)

Arthrobacter crysallopoietes strain KM-4 degrading 2,6-dimethylpyridine and strain KM-4a degrading both 2,6-dimethylpyridine and pyridine, Arthrobacter sp. KM-4b degrading 2,4-dimethylpyridine were is...

Chemical standards in ion mobility spectrometry.

Analyst 135(6) , 1433-42, (2010)

In ion mobility spectrometry (IMS), reduced mobility values (K(0)) are used as a qualitative measure of gas phase ions, and are reported in the literature as absolute values. Unfortunately, these valu...

Factors dictating the nuclearity/aggregation and acetate coordination modes of lutidine-coordinated zinc(II) acetate complexes.

Inorg. Chem. 49(1) , 62-72, (2010)

The reactions of Zn(OAc)(2).2H(2)O with various positional isomers of lutidine were explored with a view to understand the factors responsible for the nuclearity/aggregation and acetate coordination m...


More Articles

Related Compounds

  • 2,4-lutidine N-oxide
  • 5-nitro-2,4-lutidine
  • 6,6'-Bi-2,4-lutidine
  • 6-Amino-2,4-lutidine
  • 6-Phenyl-2,4-lutidine
  • 6-Chloro-2,4-lutidine
  • 2-(Furan-2-ylmethyl)cyclohexan-1-ol
  • tert-Butyl (5-amino-4-(methylamino)pyridin-2-yl)carbamate
  • 2-Methyl-5-((trimethylsilyl)ethynyl)pyrimidin-4-amine
  • N-Cyclopropyl-3-[1,6-dihydro-1-methyl-4-(methylamino)imidazo[4,5-d]pyrrolo[2,3-b]pyridin-7-yl]benzamide
  • Trimethyl-(3-methylsulfanyl-phenylethynyl)-silane
  • tert-Butyl (1-methyl-1H-imidazo[4,5-c]pyridin-6-yl)carbamate
  • tert-Butyl (4-chloro-5-nitropyridin-2-yl)carbamate
  • n-((4h-1,2,4-Triazol-3-yl)methyl)-2-(cyclopent-2-en-1-yl)-N-methylacetamide
  • 1,1-Dimethylethyl N-[6-amino-1-methyl-7-(2-phenylethynyl)-1H-imidazo[4,5-c]pyridin-4-yl]-N-methylcarbamate
  • N-[1-(6-Bromo-2-pyridinyl)propyl]acetamide
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