(E)-(4S,5S)-6-<(tert-Butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexen-1-ol

Names

[ CAS No. ]:
108818-00-4

[ Name ]:
(E)-(4S,5S)-6-<(tert-Butyldimethylsilyl)oxy>-4,5-O-(1-methylethylidene)-2-hexen-1-ol

[Synonym ]:
6-<(tert-butyldimethylsilyl)oxy>-4(S),5(S)-(isopropylidenedioxy)-2(E)-hexen-1-ol
.6-[(tert-butyldimethylsilyl)oxy]-4(S),5(S)-(isopropylidenedioxy)-2(E)-hexen-1-ol

Chemical & Physical Properties

[ Molecular Formula ]:
C15H30O4Si

[ Molecular Weight ]:
302.48200

[ Exact Mass ]:
302.19100

[ PSA ]:
47.92000

[ LogP ]:
3.07680

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (E)-methyl 3-((4S,5S)-5-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate
  • [(4S,5S)-5-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol

DownStream

  • 1-Deoxynojirimycin
  • (2S,3R,4R,5S)-6-<(tert-butyldimethylsilyl)oxy>-2,3-epoxy-4,5-(isopropylidenedioxy)hexan-1-ol
  • (2R,3R,4S,5S)-2-azido-6-<(tert-butyldimethylsilyl)oxy>-4,5-(isopropylidenedioxy)hexane-1,3-diol
  • (2S,3S,4R,5R)-5-azido-1-<(tert-butyldimethylsilyl)oxy>-2,3-(isopropylenedioxy)-4,6-bis(methoxymethoxy)hexane
  • (2S,3S,4R,5R)-5-azido-2,3-(isopropylenedioxy)-4,6-bis(methoxymethoxy)hexan-1-ol
  • (2S,3S,4R,5R)-5-azido-2,3-(isopropylenedioxy)-4,6-bis(methoxymethoxy)-1-<(methylsulfonyl)oxy>hexane
  • (2R,3R,4S,5S)-4,5-(isopropylenedioxy)-3-(methoxymethoxy)-2-<(methoxymethoxy)methyl>piperidine