Triethylene glycol dimethacrylate

Suppliers

Names

[ CAS No. ]:
109-16-0

[ Name ]:
Triethylene glycol dimethacrylate

[Synonym ]:
1,2-Ethanediylbis(oxy-2,1-ethanediyl) bis(2-methylacrylate)
Ethy
tgm3pc
TEGDMA
TEDMA
EINECS 203-652-6
MFCD00008591
triethyleneglycol dimethylacrylate
tgm3s
2-Propenoic acid, 2-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester
TGM 3
tgm35
(Ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)
Ethane-1,2-diylbis(oxyethane-2,1-diyl) bis(2-methylacrylate)
Triethylene glycol dimethacrylate
ethane-1,2-diylbis(oxyethane-2,1-diyl) bis(2-methylprop-2-enoate)

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
335.5±0.0 °C at 760 mmHg

[ Melting Point ]:
-52°C

[ Molecular Formula ]:
C14H22O6

[ Molecular Weight ]:
286.321

[ Flash Point ]:
159.1±22.4 °C

[ Exact Mass ]:
286.141632

[ PSA ]:
71.06000

[ LogP ]:
1.81

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.456

[ Storage condition ]:
2-8°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OZ4100000
CHEMICAL NAME :
Methacrylic acid, diester with triethylene glycol
CAS REGISTRY NUMBER :
109-16-0
BEILSTEIN REFERENCE NO. :
1797351
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C14-H22-O6
MOLECULAR WEIGHT :
286.36

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10837 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10750 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7889 mg/kg/26W-I
TOXIC EFFECTS :
Blood - pigmented or nucleated red blood cells

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
4 mg/plate
REFERENCE :
TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 31(Suppl),214,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1872 No. of Facilities: 106 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 1278 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1872 No. of Facilities: 357 (estimated) No. of Industries: 19 No. of Occupations: 17 No. of Employees: 12250 (estimated) No. of Female Employees: 2734 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H317

[ Precautionary Statements ]:
P280-P333 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S28

[ RIDADR ]:
UN 3334

[ WGK Germany ]:
1

[ RTECS ]:
OZ4100000

[ HS Code ]:
2918990090

Synthetic Route

Precursor & DownStream

Precursor

  • Dichlorodimethyltin
  • Mequinol
  • Methyl methacrylate
  • Methacryloyl chloride
  • Triethylene glycol
  • Methacrylic acid

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Effect of methacrylated-based antibacterial monomer on orthodontic adhesive system properties.

Am. J. Orthod. Dentofacial Orthop. 147(4 Suppl) , S82-7, (2015)

Antibacterial adhesives were developed to reduce the incidence of white spot lesions in orthodontic patients. Compounds that contain triazine are known as effective antibacterial agents. The aims of t...

Interpenetrating polymer network hydrogel scaffolds for artificial cornea periphery.

J. Mater. Sci. Mater. Med. 26(2) , 107, (2015)

Three-dimensional scaffolds based on inverted colloidal crystals (ICCs) were fabricated from sequentially polymerized interpenetrating polymer network (IPN) hydrogels of poly(ethyleneglycol) and poly(...

Bisphenol-A and residual monomer leaching from orthodontic adhesive resins and polycarbonate brackets: a systematic review.

Am. J. Orthod. Dentofacial Orthop. 143(4 Suppl) , S104-12.e1-2, (2013)

The objective of this systematic review was to assess the short- and long-term release of components of orthodontic adhesives and polycarbonate brackets in the oral environment.Electronic database sea...


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Related Compounds

  • triethylene glycol dimethacrylate
  • TRIETHYLENE GLYCOL MONOHEPTYL ETHER
  • Triethylene glycol monooctyl ether
  • Triethylene glycol bisheptanoate
  • Triethylene Glycol Monoethyl Ether
  • Triethylene glycol monododecyl ether
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