Propyl carbonochloridate

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Names

[ CAS No. ]:
109-61-5

[ Name ]:
Propyl carbonochloridate

[Synonym ]:
Chloroformic Acid Propyl Ester
MFCD00000649
Chloroformicacidpropylester
Carbonochloridic acid, propyl ester
Propyl carbonochloridate
EINECS 203-687-7

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
116.2±9.0 °C at 760 mmHg

[ Melting Point ]:
<-70ºC

[ Molecular Formula ]:
C4H7ClO2

[ Molecular Weight ]:
122.550

[ Flash Point ]:
28.9±0.0 °C

[ Exact Mass ]:
122.013458

[ PSA ]:
26.30000

[ LogP ]:
1.97

[ Vapour Pressure ]:
18.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.412

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ6830000
CHEMICAL NAME :
Formic acid, chloro-, propyl ester
CAS REGISTRY NUMBER :
109-61-5
BEILSTEIN REFERENCE NO. :
0906817
LAST UPDATED :
199709
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-H7-Cl-O2
MOLECULAR WEIGHT :
122.56
WISWESSER LINE NOTATION :
GVO3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
319 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>10 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H314-H331

[ Precautionary Statements ]:
P210-P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R10;R23;R34

[ Safety Phrases ]:
S26-S36-S45

[ RIDADR ]:
UN 2740 6.1/PG 1

[ WGK Germany ]:
1

[ RTECS ]:
LQ6830000

[ Packaging Group ]:
I

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Propanol
  • Triphosgene
  • phosgene

DownStream

  • mpc
  • 1-Chloropropane
  • 4-chlorocumene
  • cyclopropane
  • UNII:FGB8O5N903
  • Hydrochloric acid
  • propene
  • Carbon dioxide
  • Propyl carbamate

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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