Methylenaminoacetonitrile

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Names

[ CAS No. ]:
109-82-0

[ Name ]:
Methylenaminoacetonitrile

[Synonym ]:
Methyleneiminoacetonitrile
Methyleneglycinonitrile
METHYLENEAMINOACETONITRILE
2-(methylideneamino)acetonitrile
MFCD00001889
(Methyleneamino)acetonitrile
UNII:VUC4O8Q6RO
α-Hydroformamine Cyanide
alpha-Hydroformamine Cyanide
2-(methyleneamino)acetonitrile
Acetonitrile, 2-(methyleneamino)-
EINECS 203-709-5

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
151.2±40.0 °C at 760 mmHg

[ Melting Point ]:
127-130 °C

[ Molecular Formula ]:
C3H4N2

[ Molecular Weight ]:
68.077

[ Flash Point ]:
45.2±27.3 °C

[ Exact Mass ]:
68.037445

[ PSA ]:
36.15000

[ LogP ]:
0.42

[ Vapour Pressure ]:
3.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.438

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MC1925000
CHEMICAL NAME :
Glycinonitrile, N-methylene-
CAS REGISTRY NUMBER :
109-82-0
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C3-H4-N2
MOLECULAR WEIGHT :
68.09
WISWESSER LINE NOTATION :
NC1NU1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,27,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 7,689,1955

Safety Information

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S36/37/39-S26-S22

[ RTECS ]:
MC1925000

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,2',2''-(1,3,5-Triazinane-1,3,5-triyl)triacetonitrile
  • Formaldehyde
  • tetrabutylammonium cyanide
  • Sodium cyanide

DownStream

  • diethoxymethane
  • Glycinonitrile bisulfate
  • Ethyl glycinate
  • 2406 i.s.
  • Aminoacetonitrile
  • Sarcosine
  • Glycine

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine