4-Acetylphenyl Trifluoromethanesulfonate

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Names

[ CAS No. ]:
109613-00-5

[ Name ]:
4-Acetylphenyl Trifluoromethanesulfonate

[Synonym ]:
4-Acetylphenyl trifluoromethanesulfonate
MFCD00191706
(4-acetylphenyl) trifluoromethanesulfonate
Trifluoromethanesulfonic Acid 4-Acetylphenyl Ester
4-Acetylphenyl Triflate

Chemical & Physical Properties

[ Density]:
1.418 g/mL at 25 °C(lit.)

[ Boiling Point ]:
75-76 °C0.35 mm Hg(lit.)

[ Molecular Formula ]:
C9H7F3O4S

[ Molecular Weight ]:
268.21000

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
268.00200

[ PSA ]:
68.82000

[ LogP ]:
3.19840

[ Vapour Pressure ]:
0.000229mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.47(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H315-H319-H331-H335-H351

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 2810 6.1/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2914400090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • triflic anhydride
  • 4-Hydroxyacetophenone
  • N,N-Bis(trifluoromethylsulfonyl)aniline
  • Trifluoroacetic anhydride
  • Ethanone,1-[4-[(methylsulfonyl)oxy]phenyl]-

DownStream

  • 1-[4-(2-methyl-1,3-dioxolan-2-yl)phenyl]ethanone
  • BI-P-TOLYL
  • 1-(4'-Methyl-4-biphenylyl)ethanone
  • p-Butylacetophenone
  • 4-Acetylbiphenyl
  • 1-(4'-Methoxy-4-biphenylyl)ethanone
  • 1-(4'-TRIFLUOROMETHYL-BIPHENYL-4-YL)-ETHANONE
  • ETHYL 1,6-DIMETHYL-2-OXO-4-PHENYL-1,2,3,4-TETRAHYDRO-5-PYRIMIDINECARBOXYLATE
  • Biphenyl
  • Methyl 4-acetylbenzoate

Customs

[ HS Code ]: 2914400090

[ Summary ]:
2914400090 other ketone-alcohols and ketone-aldehydes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Stereochemistry of the cross-coupling reaction of chiral alkylsilanes with aryl triflates: a novel approach to optically active compounds. Hatanaka Y and Hiyama T.

J. Am. Chem. Soc. 112(21) , 7793-7794, (1990)

Chirality Transfer via the Palladium-Catalyzed Cross-Coupling Reaction of Optically Active 2-Cyclohexenylsilane: Stereochemical and Mechanistic Aspects. Hiyama T, et al.

Organometallics 15(26) , 5762-5765, (1996)

Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation. Liu S and Zhou JS.

Chem. Commun. (Camb.) 49(100) , 11758-11760, (2013)


More Articles

Related Compounds

  • 6-Bromo-4,8-dimethyl-2-(piperazin-1-yl)quinoline hydrochloride
  • 6-Bromo-4,8-dimethyl-2-hydrazinoquinoline hydrochloride
  • 6-Bromo-4-methyl-2-(piperazin-1-yl)quinoline hydrochloride
  • 6-Bromo-8-methyl-2-phenyl-4-(piperazin-1-yl)quinoline hydrochloride
  • 6-Bromo-8-methyl-4-(piperazin-1-yl)-2-propylquinoline hydrochloride
  • 6-Bromo-8-methylquinoline-3-carbohydrazide
  • 6-Bromo-8-methyl-4-(piperazin-1-yl)quinoline hydrochloride
  • 6-Chloro-2,8-dimethyl-4-(piperazin-1-yl)quinoline hydrochloride
  • 6-Chloro-2-hydrazino-4-methylquinoline hydrochloride
  • 6-Chloro-2-phenyl-4-(piperazin-1-yl)quinoline hydrochloride
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