Isopentyl nitrite

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Names

[ CAS No. ]:
110-46-3

[ Name ]:
Isopentyl nitrite

[Synonym ]:
Amyl Nitrite
Isoamyl nitrite,stabilized
ISO-PENTYLNITRITE
3-METHYLBUTYLNITRIT
ISOAMYL NITRITE/ AMYL NITRITE/ISOPENTYL NITRITE/3-METHYLBUTYL NITRITE/ NITROUS ACID 3-METHYLBUTYL ESTER
Isopentyl nitrite
Nitrous acid, 3-methylbutyl ester
ISOAMYLNITRIT
ISOAMYL NITRITE (100 ML )
Nitramyl
isopentanol nitrite
Isoamylnitrite
Nitrous acid 3-methylbutyl ester
ISOAMYNITRILE
pentyl nitrite
nitrous acid isopentyl ester
Iso-Amyl Nitrite
isopentyl alcohol nitrite
ISOPENTYLNITRITE =3-METHYLBUTYLNITRITE
EINECS 203-770-8
3-Methylbutyl nitrite
Isoamyl Nitrite
ISOPENTYL NITRITE / ISOAMYL NITRITE
MFCD00002057

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
99.1±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H11NO2

[ Molecular Weight ]:
117.146

[ Flash Point ]:
10.0±0.0 °C

[ Exact Mass ]:
117.078979

[ PSA ]:
38.66000

[ LogP ]:
2.45

[ Vapour Pressure ]:
44.6±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.425

[ Stability ]:
Stability Unstable. Air and light sensitive. Flammable. Forms explosive mixtures with air or oxygen. Incompatible with oxidizing agents, reducing agents.

[ Water Solubility ]:
<0.01 g/100 mL at 18 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NT0187500
CHEMICAL NAME :
Isopentyl alcohol, nitrite
CAS REGISTRY NUMBER :
110-46-3
BEILSTEIN REFERENCE NO. :
0969510
LAST UPDATED :
199701
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C5-H11-N-O2
MOLECULAR WEIGHT :
117.17
WISWESSER LINE NOTATION :
ONO2Y

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
505 mg/kg
TOXIC EFFECTS :
Behavioral - general anesthetic
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
716 ppm/4H
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex) Behavioral - excitement Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1430 ppm/30M
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay)
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
130 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
51 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
167 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
16 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83996 No. of Facilities: 33 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 33 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H331

[ Precautionary Statements ]:
P210-P261-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R20/22

[ Safety Phrases ]:
S16-S24-S46

[ RIDADR ]:
UN 1113 3/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
NT0187500

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Methyl-1-butanol
  • Benzene,[(3-methylbutoxy)methyl]-
  • nitrous acid
  • Isoamyl bromide
  • Nitrous acid, methylester

DownStream

  • 3-nitro-2,4,5-triphenyl-1H-pyrrole
  • 2-Phenyl-1,3-Propanediamine
  • Phenibut
  • barbital
  • Ethyl 5-thiazolecarboxylate
  • diisoamylamine
  • Triisoamylamine
  • 3-Methyl-1-butylamine
  • 3-Methylbutanenitrile
  • N-Benzyl-N-nitroso-1-phenylmethanamine

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Related Compounds

  • Isopentyl nitrite-15N
  • Isopentyl 5-bromopentanoate
  • isopentyl 2-((methylthio)methyl)-3-oxobutanoate
  • isopentyl hexanoate
  • isopentyl 4-hydroxybenzoate
  • isopentyl (4-chloro-2-methylphenoxy)acetate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine