Valeronitrile

Suppliers

Names

[ CAS No. ]:
110-59-8

[ Name ]:
Valeronitrile

[Synonym ]:
Butyl Cyanide
pentanenitrile
Butyl cyanide,Pentanenitrile
EINECS 203-781-8
MFCD00001974

Chemical & Physical Properties

[ Density]:
0.795 g/mL at 25 °C(lit.)

[ Boiling Point ]:
139-141 °C(lit.)

[ Melting Point ]:
−96 °C(lit.)

[ Molecular Formula ]:
C5H9N

[ Molecular Weight ]:
83.13170

[ Flash Point ]:
105 °F

[ Exact Mass ]:
83.07350

[ PSA ]:
23.79000

[ LogP ]:
1.70018

[ Index of Refraction ]:
n20/D 1.397(lit.)

[ Stability ]:
Stable. Incompatible with strong acids, strong bases, strong oxidizing agents, strong reducing agents. Flammable.

[ Water Solubility ]:
0.1-0.5 g/100 mL at 22.5 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YV8195000
CHEMICAL NAME :
Valeronitrile
CAS REGISTRY NUMBER :
110-59-8
BEILSTEIN REFERENCE NO. :
1736706
LAST UPDATED :
199710
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C5-H9-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
191 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 55,47,1984 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
525 mg/kg/3D-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - urine volume increased Kidney, Ureter, Bladder - other changes in urine composition
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,149,1988 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7310 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 7 No. of Employees: 312 (estimated) No. of Female Employees: 6 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301

[ Precautionary Statements ]:
P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R10;R25

[ Safety Phrases ]:
S36/37/39-S45-S16

[ RIDADR ]:
UN 1992 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
YV8195000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29332100

Synthetic Route

Precursor & DownStream

Precursor

  • Oxirane, 2-butyl-
  • n-pentanaldehyde oxime
  • Pentanoic acid
  • Valeraldehyde
  • n-Hexanamide
  • pent-3-enenitrile
  • carbon monoxide
  • N-HYDROXY-PENTANAMIDINE
  • 1-Bromobutane
  • Sodium cyanide

DownStream

  • methyl valerimidate hydrochloride
  • Amylamine hydrochloride
  • 5-Nonanone
  • 5-Nonanol, 5-butyl-
  • Cyclopentanamine,N-cyclopentyl-
  • pentanol
  • isopropyl valerate
  • PENTANIMIDAMIDE HYDROCHLORIDE
  • Pentanoic acid
  • ZV4

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Novel organic solvents for electrochemistry at the liquid/liquid interface.

Analyst 140(6) , 1947-54, (2015)

Two-phase voltammetry has been carried out using a reverse cell configuration, i.e. with the lower density organic solvent on the top of the aqueous solution in the cell, where the organic solvents co...

Molecularly imprinted polymers for cleanup and selective extraction of curcuminoids in medicinal herbal extracts.

Anal. Bioanal. Chem 407(3) , 803-12, (2015)

This paper describes the synthesis of novel molecularly imprinted polymers (MIPs), prepared by a noncovalent imprinting approach, for cleanup and preconcentration of curcumin (CUR) and bisdemethoxycur...

Anatase TiO2 Nanoparticles with Exposed {001} Facets for Efficient Dye-Sensitized Solar Cells.

Sci. Rep. 5 , 12143, (2015)

Anatase TiO2 nanoparticles with exposed {001} facets were synthesized from Ti powder via a sequential hydrothermal reaction process. At the first-step hydrothermal reaction, H-titanate nanowires were ...


More Articles


Related Compounds

  • iodovaleronitrile
  • bromovaleronitrile
  • Valeronitrile dimer
  • 5-oxo-valeronitrile
  • 2-oxo-valeronitrile
  • 4-bromovaleronitrile
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 3-(3-Ethoxy-4-methoxyphenyl)azetidine
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 8-Bromo-3,4-dihydrospiro[1,4-benzoxazine-2,1'-cyclopropane]
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine