3-Methoxypropionitrile

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Names

[ CAS No. ]:
110-67-8

[ Name ]:
3-Methoxypropionitrile

[Synonym ]:
3-Methoxypropanenitrile
MFCD00001958
3-Methoxypropionitrile
EINECS 203-790-7
Propanenitrile, 3-methoxy-
β-Methoxypropionitrile

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
163.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-62.9 °C

[ Molecular Formula ]:
C4H7NO

[ Molecular Weight ]:
85.104

[ Flash Point ]:
61.1±0.0 °C

[ Exact Mass ]:
85.052765

[ PSA ]:
33.02000

[ LogP ]:
-0.44

[ Vapour Pressure ]:
2.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.388

[ Water Solubility ]:
335 g/L (20 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ4870000
CHEMICAL NAME :
Propanenitrile, 3-methoxy-
CAS REGISTRY NUMBER :
110-67-8
BEILSTEIN REFERENCE NO. :
1739284
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C4-H7-N-O
MOLECULAR WEIGHT :
85.12
WISWESSER LINE NOTATION :
NC2O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4390 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,916,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2900 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>10 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
3276

[ WGK Germany ]:
2

[ RTECS ]:
TZ4870000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • Acrylonitrile
  • 2-Cyanoethyl nitrate
  • 3-methoxypropanamide
  • methyl chloroacetate
  • Sodium Methylate
  • hydracrylonitrile
  • Dimethyl Carbonate
  • methyl formate
  • diazomethane

DownStream

  • 3-(4-MORPHOLINO)PROPIONITRILE
  • 1-Piperidinepropionitrile
  • 2,2-Dimethylpropanamide
  • 3-methoxypropanamide
  • 3-Butoxypropionitrile
  • 5-Methoxy-3-oxovaleric acid methyl ester
  • 3-(butylamino)propionitrile
  • 3-(Benzyloxy)propanenitrile
  • 3-Methoxypropylamine
  • Bis(3-methoxypropyl)amine

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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