1-Bromohexane

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Names

[ CAS No. ]:
111-25-1

[ Name ]:
1-Bromohexane

[Synonym ]:
1-bromo-hexan
HEXYL BROMIDE, N-
1-BROMO HEXANE
1-hexylbromide
HEXYLBROMIDE
HEXANE,1-BROMO-
EINECS 203-850-2
n-hexyl bromide
HEXYL BROMIDE
1-BROMO HEPTANE
1-BROMHEXAN
hexane,1-bromo
N-BROMOHEXANE
Hexane, 1-bromo-
1-BROMOHEXANE FOR SYNTHESIS
N-HEXYLBROMIDE
MFCD00000271
1-BROMOHEXANE/N-HEXYL BROMIDE
Hexylbromid
1-BROMO-HEXANE
Bromohexane
1-bromo-n-hexane
1-Bromohexane
1-Bromohexan
N-Hexyl romide

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
154.9±3.0 °C at 760 mmHg

[ Melting Point ]:
−85 °C(lit.)

[ Molecular Formula ]:
C₆H₁₃Br

[ Molecular Weight ]:
165.071

[ Flash Point ]:
57.2±0.0 °C

[ Exact Mass ]:
164.020050

[ LogP ]:
3.81

[ Vapour density ]:
5.7 (vs air)

[ Vapour Pressure ]:
4.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.447

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO0925000

CHEMICAL NAME :: Hexane, 1-bromo-

CAS REGISTRY NUMBER :: 111-25-1

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C6-H13-Br

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 550 gm/m3/30M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FAVUAI Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. (Izdatel'stvo Naukova Dumka, Kiev, USSR) No.1- 1966- Volume(issue)/page/year: 7,35,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1226 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 20(12),52,1976

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 13600 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(4),55,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3 JAN 1993

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S36-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
MO0925000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29033036

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

chloro(hexyl)mercury
1-bromo-5-hexene
1-Hexanol
3-BROMOHEXANE
chlorohexane
2-BROMOHEXANE
1,6-hexanediylmercury
1-Hexen-3-ol
1-ETHOXYHEXANE

DownStream

methyl n-hexylsulfonate
1-(3-hexoxyphenyl)-3-hydroxyprop-2-en-1-one
N,N-DIMETHYL-N-(1-HEXYL)-N-(2-[METHACRYLOYL]ETHYL)AMMONIUM BROMIDE
3-(hexylamino)phenol
3-methylidenedec-1-yne
3,3'-Bithienyl
3-(1-methylpentyl)thiophene
3-hexylthiophene
N-HEXYLPHOSPHONIC ACID
4-Hexylanilin

Customs

[ HS Code ]: 2903399090

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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