(E)-3-((2R,3R,6S)-3-((tert-butyldimethylsilyl)oxy)-6-ethoxy-3,6-dihydro-2H-pyran-2-yl)acrylaldehyde

Names

[ CAS No. ]:
111397-80-9

[ Name ]:
(E)-3-((2R,3R,6S)-3-((tert-butyldimethylsilyl)oxy)-6-ethoxy-3,6-dihydro-2H-pyran-2-yl)acrylaldehyde

Chemical & Physical Properties

[ Molecular Formula ]:
C16H28O4Si

[ Molecular Weight ]:
312.47700

[ Exact Mass ]:
312.17600

[ PSA ]:
44.76000

[ LogP ]:
3.44950

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ethyl 4-O-tert-butyldimethylsilyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

DownStream

  • Asperlin 224b
  • tert-butyl(((2R,3R,6S)-6-ethoxy-2-((2R,3S)-3-methyloxiran-2-yl)-3,6-dihydro-2H-pyran-3-yl)oxy)dimethylsilane
  • ba-L-galacto-Oct-2-enopyranoside, ethyl 6,7-anhydro-2,3,8-trideoxy- (9CI)
  • (2S,3R,6S)-6-ethoxy-2-((2R,3S)-3-methyloxiran-2-yl)-3,6-dihydro-2H-pyran-3-yl acetate