trimethylsilyl isocyanate

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Names

[ CAS No. ]:
1118-02-1

[ Name ]:
trimethylsilyl isocyanate

[Synonym ]:
trimethylsilylisocyanate
Isocyanatotrimethylsilane
EINECS 214-256-8
Isocyanato(trimethyl)silane
MFCD00001993
Silane, isocyanatotrimethyl-
Trimethylsilyl isocyanate
Isocyanato-Trimethylsilane

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
91.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-49°C

[ Molecular Formula ]:
C4H9NOSi

[ Molecular Weight ]:
115.206

[ Flash Point ]:
5.7±22.6 °C

[ Exact Mass ]:
115.045341

[ PSA ]:
29.43000

[ LogP ]:
2.16

[ Vapour Pressure ]:
62.1±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.410

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H319-H331-H334-H335

[ Precautionary Statements ]:
P210-P261-P284-P304 + P340 + P312-P342 + P311-P403 + P233

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,T

[ Risk Phrases ]:
11-23-36/37-42

[ Safety Phrases ]:
S23-S26-S36/37/39-S45

[ RIDADR ]:
UN 2478 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • Silver cyanate
  • Sodium cyanate
  • Potassium cyanate
  • Bis(trimethylsilyl) sulfate
  • Dipropylphosphorisocyanatidit
  • N,N-Diethyl-1,1,1-trimethylsilanamine
  • Urea
  • (2,2,2-trifluoro-1,1-diisocyanato-ethyl)-benzene

DownStream

  • 4-ethylbenzamide
  • 2,6-Difluorobenzoyl isocyanate
  • 1-Adamantyl isocyanate
  • 3,4-dimethylbenzamide
  • Benzamide
  • 1,4-dioxa-8-azaspiro[4.5]decane-8-carboxamide
  • 5-(1H-indol-3-ylmethyl)imidazolidine-2,4-dione
  • Hydrazinecarboxamide,1-methyl-
  • Bromo(trimethyl)silane

Articles

Geiparvarin analogues. 4. Synthesis and cytostatic activity of geiparvarin analogues bearing a carbamate moiety or a furocoumarin fragment on the alkenyl side chain.

J. Med. Chem. 37 , 2401, (1994)

As a continuation of previous studies on the synthesis and antitumor activity of geiparvarin analogues bearing a carbamate moiety in the alkyl side chain, a series of N-substituted [(E)-3-(4,5-dihydro...

Covalent modification of a metal-organic framework with isocyanates: probing substrate scope and reactivity.

Chem. Commun. (Camb.) (29) , 3366-8, (2008)

Isoreticular metal-organic framework-3 (IRMOF-3) has been postsynthetically modified with isocyanates to generate unprecedented, microporous urea-functionalized frameworks.

J. Prakt. Chem./Chem.-Ztg. 335 , 558, (1993)


More Articles

Related Compounds

  • Trimethylsilyl isocyanate
  • trimethylsilyl 2-((trimethylsilyl)oxy)butanoate
  • Trimethylsilyl benzenesulfonate
  • trimethylsilyl 2-(1-methylpyrrol-3-yl)acetate
  • trimethylsilyl 4-(isocyanatomethyl)benzoate
  • trimethylsilyl 2-(1-((((1-chloroethoxy)carbonyl)amino)methyl)cyclohexyl)acetate
  • 1,1-Dimethylethyl N-[3-[7-[2-(4-cyano-2-fluorophenoxy)ethyl]-9-oxa-3,7-diazabicyclo[3.3.1]non-3-yl]propyl]carbamate
  • 14-Phenyl-9-pyridin-3-yl-3,7-dithia-5,14-diazapentacyclo[9.5.1.02,10.04,8.012,16]heptadec-4(8)-ene-6,13,15-trione
  • 1-[3,4-Bis[(4-methoxyphenyl)methoxy]phenyl]ethanone
  • N-(3,4-Dimethoxyphenyl)-1-ethyl-1H-pyrazole-5-methanamine
  • Arsinothious acid, bis(trifluoromethyl)-, trifluoromethyl ester
  • Naphtho[1,2-b]pyrylium, 5,6-dihydro-2,4-diphenyl-, perchlorate
  • 2,4-Diphenyl-5,6-dihydrobenzo[h]chromenium thiocyanate
  • Piperidine, 1-(1-oxo-2,4-eicosadienyl)-, (E,E)-
  • 4,4,5,5-Tetramethyl-2-((1R,2S)-2-phenylcyclohexyl)-1,3,2-dioxaborolane
  • 4-(4-Methylphenyl)-2,6-diphenyl-1,4-pyran-1-ylium perchlorate
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