H-Glu(OEt)-OEt.HCl

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Names

[ CAS No. ]:
1118-89-4

[ Name ]:
H-Glu(OEt)-OEt.HCl

[Synonym ]:
L-Glutamic acid, diethyl ester, hydrochloride (1:1)
Glutamic acid, diethyl ester, hydrochloride (1:1)
diethyl (2S)-2-aminopentanedioate,hydrochloride
MFCD00012509
Diethyl L-Glutamate Hydrochloride
Diethyl L-glutamate hydrochloride (1:1)
H-Glu(OEt)-OEt·HCl
Diethyl glutamate hydrochloride (1:1)
L-Glutamic Acid Diethyl Ester Hydrochloride
EINECS 214-270-4
H-Glu(OEt)-OEt.HCl

Chemical & Physical Properties

[ Density]:
1.08g/cm3

[ Boiling Point ]:
262ºC at 760 mmHg

[ Melting Point ]:
108-110 °C(lit.)

[ Molecular Formula ]:
C9H18ClNO4

[ Molecular Weight ]:
239.697

[ Flash Point ]:
86.3ºC

[ Exact Mass ]:
239.092438

[ PSA ]:
78.62000

[ LogP ]:
1.72240

[ Vapour Pressure ]:
0.0112mmHg at 25°C

[ Index of Refraction ]:
22.5 ° (C=3.6, EtOH)

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MA1252280
CHEMICAL NAME :
L-Glutamic acid, diethyl ester, hydrochloride
CAS REGISTRY NUMBER :
1118-89-4
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C9-H17-N-O4.Cl-H
MOLECULAR WEIGHT :
239.73

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 25,246,1991

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
MA1252280

[ HS Code ]:
2922499990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethanol
  • L-glutamic acid

DownStream

  • H-Glu-Glu-OH
  • Edatrexate
  • H-Pyr-OEt
  • 5,10-methylene-5,6,7,8-tetrahydro-8,10-dideazaminopterin
  • diethyl (2S)-2-pyrrol-1-ylpentanedioate
  • Diethyl N-[5-methylamino-2-thenoyl]-L-glutamate
  • PEMETREXED DIETHYL ESTER (L-GLUTAMIC ACID, N-[4-[2-(2-AMINO-4,7-DIHYDRO-4-OXO-3H-PYRROLO[2,3-D]PYRIMIDIN-5-YL)ETHYL]BENZOYL]-, 1,5-DIETHYL ESTER )
  • (S)-(-)-2-HYDROXY-3,3-DIMETHYLBUTYRICACID
  • Raltitrexed
  • Diethyl N-[5-[N-[(3,4-dihydro-2-methyl-4-oxo-6-quinazolinyl)methyl]-N-methylamino]-2-thenoyl]-L-glutamate

Customs

[ HS Code ]: 2922499990

[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • H-Glu(OEt)-OH
  • H-Glu(Met-OH)-OH
  • H-D-Glu-Oet
  • H-D-Asp(OEt)-OEt.HCl
  • H-Glu(Leu-OH)-OH
  • H-Glu-Asn-Asp-Tyr(PO3H2)-Ile-Asn-Ala-Ser-Leu-OH
  • 4-(4-Chlorophenyl)-3-[(phenylmethylene)amino]-2(3H)-thiazolethione
  • 2-(2-Benzoxazolylamino)-1,4-dihydro-4-oxo-5-pyrimidinecarbonitrile
  • Glycine, N-[N-[(phenylmethoxy)carbonyl]-L-isoleucyl]-, ethyl ester
  • Octanoic acid, 2-hydroxy-3-nitrilo-6-oxy-, 1,1-dimethylethyl ester
  • 2-[4-[2-Cyano-2-(2,4-dichlorophenyl)ethenyl]phenoxy]propanoic acid
  • Ethyl 2-[3-hydroxy-4-(1-oxo-3-phenyl-2-propen-1-yl)phenoxy]acetate
  • Cholesta-9(11),17(20)-dien-23-one, 3,6-dihydroxy-, (3I(2),5I+/-,6I+/-,17E)-
  • Pyridine, 2-chloro-6-methyl-5-nitro-3-[4-(trifluoromethyl)phenyl]-
  • O-I(2)-D-Xylopyranosyl-(1a5)-O-I+/--L-arabinofuranosyl-(1a3)-L-arabinose
  • 2,3,4,6-Tetrahydro-2-(phenylmethyl)-1H-pyrido[4,3-b]carbazol-1-one
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