(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&

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Names

[ CAS No. ]:
111822-69-6

[ Name ]:
(R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-&

[Synonym ]:
3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diol
[1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis(triphenylsilyl)-

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Melting Point ]:
103-145ºC

[ Molecular Formula ]:
C56H42O2Si2

[ Molecular Weight ]:
803.102

[ Exact Mass ]:
802.272339

[ PSA ]:
40.46000

[ LogP ]:
16.28

[ Index of Refraction ]:
1.744

Safety Information

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

Articles

Enantioselective direct aza hetero-Diels-Alder reaction catalyzed by chiral Brønsted acids.

Org. Lett. 8 , 6023, (2006)

[Structure: see text] The first chiral Brønsted acid-catalyzed asymmetric direct aza hetero-Diels-Alder reaction has been described. The phosphoric acids, prepared from binol and H8-binol derivatives,...

3,3'-Bis(trisarylsilyl)-substituted binaphtholate rare earth metal catalysts for asymmetric hydroamination.

J. Am. Chem. Soc. 128 , 3748, (2006)

Chiral 3,3'-bis(trisarylsilyl)-substituted binaphtholate rare earth metal complexes (R)-[Ln{Binol-SiAr3}(o-C6H4CH2NMe2)(Me2NCH2Ph)] (Ln = Sc, Lu, Y; Binol-SiAr3 = 3,3'-bis(trisarylsilyl)-2,2'-dihydrox...


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Related Compounds

  • R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol
  • (r)-(-)-3,3'-bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol
  • R-3,3'-Bis(4-methylphenyl)-1,1'-bi-2-naphthol
  • R-3-3'-Bis(3,5-bis(methyl)phenyl)-1,1'-bi-2-naphthol
  • R-3,3'-bis(1-Naphthyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol