Methyl nonyl ketone

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Names

[ CAS No. ]:
112-12-9

[ Name ]:
Methyl nonyl ketone

[Synonym ]:
UNII-YV5DSO8CY9
Methyl-nonyl-keton-<2.4-dinitro-phenylhydrazon>
Methyl-n-nonylketone
undecan-2-one
EINECS 203-937-5
2-Oxoundecane
2-hendecanone
nonyl methyl ketone
10-undecanal
Methyl-n-nonylketon-2,4-DNPH
Undecan-2-on-<2.4-dinitro-phenylhydrazon>
2-Undecanon-2,4-dinitrophenylhydrazon
MFCD00009583
Methyl nonyl ketone
Methyl n-nonyl ketone
2-Undecanone

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
230.8±3.0 °C at 760 mmHg

[ Melting Point ]:
11-13 °C(lit.)

[ Molecular Formula ]:
C11H22O

[ Molecular Weight ]:
170.292

[ Flash Point ]:
88.9±0.0 °C

[ Exact Mass ]:
170.167068

[ PSA ]:
17.07000

[ LogP ]:
4.09

[ Vapour density ]:
5.9 (vs air)

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.425

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.

[ Water Solubility ]:
INSOLUBLE

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YQ2820000
CHEMICAL NAME :
2-Undecanone
CAS REGISTRY NUMBER :
112-12-9
BEILSTEIN REFERENCE NO. :
1749573
LAST UPDATED :
199712
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C11-H22-O
MOLECULAR WEIGHT :
170.33
WISWESSER LINE NOTATION :
9V1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C201,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3880 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
APJUA8 Acta Pharmaceutica Jugoslavica. (FDH, Masarykova 2, 41000 Zagreb, Yugoslavia) V.1-41, 1951-1991. Volume(issue)/page/year: 12,79,1962
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 13,869,1975 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
1 gm/kg
SEX/DURATION :
female 1-20 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - female fertility index (e.g. # females pregnant per # sperm positive females; # females pregnant per # females mated)
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 18,1024,1975 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5184 No. of Facilities: 669 (estimated) No. of Industries: 6 No. of Occupations: 12 No. of Employees: 9071 (estimated) No. of Female Employees: 6864 (estimated)

Safety Information

[ Symbol ]:

GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H410

[ Precautionary Statements ]:
P273-P501

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R51/53

[ Safety Phrases ]:
S23-S24/25-S61

[ RIDADR ]:
UN3082

[ WGK Germany ]:
2

[ RTECS ]:
YQ2820000

[ Packaging Group ]:
III

[ Hazard Class ]:
9

[ HS Code ]:
2914190090

Synthetic Route

Precursor & DownStream

Precursor

  • O-Ethyl N-Cyclohexylthiocarbamate
  • 1-Undecene
  • 2-Undecanol
  • ethyl 2-acetyl decanoate
  • 1-chloroheptane,manganese
  • Methyl vinyl ketone
  • 2-Undecanone tosylhydrazone
  • Aziridine, 1-cyclohexyl-2-methylene- (9CI)
  • undec-3-en-2-one
  • METHYLLITHIUM

DownStream

  • 2-methyl undecanol
  • Undecyl Ether
  • 3-octylundecan-2-one
  • 10-Nonadecanone
  • 4,4'-Dinonyl-2,2'-bithiazole
  • triethyl(undecan-2-yloxy)silane
  • 2-Undecanone,2-(2,4-dinitrophenyl)hydrazone
  • Bromoform
  • Decanoic acid
  • octene

Customs

[ HS Code ]: 2914190090

[ Summary ]:
2914190090 other acyclic ketones without other oxygen function。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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Related Compounds

  • METHYL NONYL KETONE, 2-HENDECANONE
  • methyl-nonyl-amine, hydrochloride
  • methyl-nonyl-malonic acid diethyl ester
  • 1-(2-hydroxy-5-methylphenyl)decan-1-one
  • 2-Heptanone, semicarbazone
  • biphenyl methyl ketone phenyl hydazone
  • 5-nitro-1-(6-piperazin-1-yl-pyridazin-3-yl)-2,3-dihydro-1H-indole
  • 1-(4-Chloro-2-pyrimidinyl)-2,3-dihydro-5-nitro-1H-indole
  • 1,1-Dimethylethyl 2-[5-[[(3,5-dichlorophenyl)sulfonyl]amino]-2,3-dihydro-1H-indol-1-yl]-1H-imidazole-1-carboxylate
  • 3,5-Dibromo-N-1H-indol-5-ylbenzenesulfonamide
  • (6-Bromo-pyridin-3-yl)-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-amine
  • 3-Iodo-6-(methylsulfinyl)pyridazine
  • 2-[(6-Iodo-3-pyridazinyl)oxy]-N,N-dimethylethanamine
  • 1-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-2,3-dihydro-5-nitro-1H-indole
  • 1,1-Dimethylethyl N-[2-[(5-bromo-2-pyrazinyl)amino]ethyl]carbamate
  • 5-Nitro-1-[5-(1-piperazinyl)-2-pyrazinyl]-1H-indole
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