DIHEXYL ETHER

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Names

[ CAS No. ]:
112-58-3

[ Name ]:
DIHEXYL ETHER

[Synonym ]:
MFCD00009525
Dihexyl Ether
EINECS 203-987-8
1-hexoxyhexane

Chemical & Physical Properties

[ Density]:
0.793 g/mL at 25 °C(lit.)

[ Boiling Point ]:
228-229 °C(lit.)

[ Melting Point ]:
-43°C

[ Molecular Formula ]:
C12H26O

[ Molecular Weight ]:
186.33400

[ Flash Point ]:
173 °F

[ Exact Mass ]:
186.19800

[ PSA ]:
9.23000

[ LogP ]:
4.16360

[ Vapour Pressure ]:
0.148mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.4204(lit.)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KN8600000
CHEMICAL NAME :
Ether, dihexyl
CAS REGISTRY NUMBER :
112-58-3
BEILSTEIN REFERENCE NO. :
1738177
LAST UPDATED :
199806
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C12-H26-O
MOLECULAR WEIGHT :
186.38
WISWESSER LINE NOTATION :
6O6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/13/1971 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
30900 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
885 mg/kg
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex)
REFERENCE :
APTOA6 Acta Pharmacologica et Toxicologica. (Copenhagen, Denmark) V.1-59, 1945-86. For publisher information, see PHTOEH Volume(issue)/page/year: 37,56,1975
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
6 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/13/1971

Safety Information

[ Hazard Statements ]:
H413

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
66

[ Safety Phrases ]:
S26-S36/37/39

[ WGK Germany ]:
2

[ RTECS ]:
KN8600000

[ HS Code ]:
2909199090

Synthetic Route

Precursor & DownStream

Precursor

  • Hexanal
  • 1-Hexanol
  • 1-Iodohexane
  • 5-pentyl-3-phenyl-1,2,4-trioxolan
  • Butanol
  • butyl acetate
  • 2-hexoxyacetic acid
  • 1-Hexanoic acid
  • Hexyl hexanoate
  • BIS(CHLOROMETHYL) ETHER

DownStream

  • hexanoyl fluoride
  • Hexyl hexanoate
  • Hexanal
  • 1-Hexanol
  • 1-hexene
  • 1-Hexanoic acid
  • perfluorohexanoyl fluoride
  • hexyl formate
  • amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)
  • Hexyl acetate

Customs

[ HS Code ]: 2909199090

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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