Methyl oleate

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Names

[ CAS No. ]:
112-62-9

[ Name ]:
Methyl oleate

[Synonym ]:
Kemester 115
Kemester 104
methyl cis-9-octadecenoate
Kemester 105
Emery 2219
Methyl cis-9-octadecenoate C18:1
Methyl cis-9-octadecenoate,Oleic acid methyl ester
emerest2801
methyl 9-octadecenoate
Esterol 112
Methyl Oleate
Methyloleat
(Z)-9-Octadecenoic acid methyl ester
Emerest 2301
EINECS 203-992-5
Oleic Acid Methyl Ester
Emery 2301
MFCD00009578

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
351.4±0.0 °C at 760 mmHg

[ Melting Point ]:
-20 °C

[ Molecular Formula ]:
C19H36O2

[ Molecular Weight ]:
296.488

[ Flash Point ]:
92.4±20.4 °C

[ Exact Mass ]:
296.271515

[ PSA ]:
26.30000

[ LogP ]:
8.16

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.454

[ Storage condition ]:
−20°C

[ Stability ]:
Stable, but air and light sensitive. Incompatible with strong oxidizing agents. Combustible.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RK0895000
CHEMICAL NAME :
Oleic acid, methyl ester, cis-
CAS REGISTRY NUMBER :
112-62-9
LAST UPDATED :
199706
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C19-H36-O2
MOLECULAR WEIGHT :
296.55
WISWESSER LINE NOTATION :
9U8VO1 -C

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
54 gm/kg/45W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - leukemia Skin and Appendages - tumors
REFERENCE :
AMBPBZ Acta Pathologica et Microbiologica Scandinavica, Section A: Pathology. (Copenhagen, Denmark) V.78-89, 1970-81. For publisher information, see ACPADQ. Volume(issue)/page/year: 82,127,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:STEL 10 ppm JAN 1993 OEL-BELGIUM:STEL 10 ppm JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg/m3 (resp. dust) JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83646 No. of Facilities: 2265 (estimated) No. of Industries: 45 No. of Occupations: 43 No. of Employees: 31786 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83646 No. of Facilities: 3726 (estimated) No. of Industries: 43 No. of Occupations: 40 No. of Employees: 36455 (estimated) No. of Female Employees: 1254 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H304-H315-H336-H410

[ Precautionary Statements ]:
P210-P261-P273-P301 + P310-P331-P501

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F,Xn,N

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S23-S24/25-S62-S61-S60-S33-S29-S16-S9

[ RIDADR ]:
UN 1206 3/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
RK0895000

[ HS Code ]:
29161500

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • Glycerine trioleate
  • oleic acid
  • Methyl 9-octadecynoate
  • [(E)-octadec-9-enoyl] (E)-octadec-9-enoate
  • Benzaldehyde dimethyl acetal
  • Trimethyl orthoformate
  • methyl 8-[(2R,3S)-3-octyloxiran-2-yl]octanoate
  • (Trimethylsilyl)diazomethane

DownStream

  • Octadecanehydrazide
  • glycidyl oleate
  • (Z)-9-Octadecenoic acid 2,2-dimethyl-1,3-dioxolan-4-ylmethyl ester
  • 1-Linoleoyl-2,3-isopropylidene-rac-glycerol
  • Hexadecanoic acid 2,2-dimethyl-1,3-dioxolan-4-ylmethyl ester
  • methane
  • N-HEPTADECANE
  • n-Octadecane
  • Methyl stearate
  • Octadecyl stearate

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

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