3-Iodopyridine

Names

[ Name ]:
3-Iodopyridine

[Synonym ]:
3-pyridine iodide
3-IODOPYRAZOLOPYRIDINE
3-Pyridyl iodide
3-lodopyridine
Pyridine,3-iodo
EINECS 214-322-6
3-pyridyl-I
3-Iodo Pyrdine
3-I-pyridine
MFCD00023553
3-iodo-pyridine

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
215.4±13.0 °C at 760 mmHg

[ Melting Point ]:
53-56 °C(lit.)

[ Molecular Formula ]:
C₅H₄IN

[ Molecular Weight ]:
204.996

[ Flash Point ]:
84.1±19.8 °C

[ Exact Mass ]:
204.938828

[ PSA ]:
12.89000

[ LogP ]:
1.80

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.630

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24/25;R36/37/38

[ Safety Phrases ]:
S26-S36-S45-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3-Pyridylboronic acid
3-Aminopyridine
3-Bromopyridine
chloro(pyridin-3-yl)mercury
dipyridin-3-ylmercury
mercury(II) nicotinate
TRIMETHYL(3-PYRIDYL)TIN
Nicotinic acid
(5-iodo-2-pyridinyl)triphenylphosphonium iodide
Pivaldehyde

DownStream

3-azidopyridine
6-bromo-2,3'-bipyridine
Phenyl(3-pyridinyl)methanone
Acetamide,N-3-pyridinyl-
Pyridine
Myosmine
3-(3-Nitrophenyl)pyridine
Nicotinaldehyde
3-ethoxy-1-pyridin-3-ylprop-2-en-1-one
3-(4-BROMOBENZOYL)PYRIDINE

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

One-pot synthesis of 1,4-disubstituted 1,2,3-triazoles from in situ generated azides.

Org. Lett. 6(22) , 3897-9, (2004)

[reaction: see text] 1,4-Disubstituted 1,2,3-triazoles are obtained in excellent yields by a convenient one-pot procedure from a variety of readily available aromatic and aliphatic halides without iso...

Synthesis of pyridine alkaloids via Pd-catalyzed coupling of 3-iodopyridine, 1, ?-dienes and nitrogen nucleophiles. Larock RC and Wang Y.

Tetrahedron Lett. 43(1) , 21-23, (2002)

Microwave-assisted solvent-and ligand-free copper-catalysed cross-coupling between halopyridines and nitrogen nucleophiles. Ernst, R. F.

Green Chem. 13(1) , 42-45, (2011)