(R,R)-(-)-1,2-Diaminocyclohexane

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Names

[ CAS No. ]:
1121-22-8

[ Name ]:
(R,R)-(-)-1,2-Diaminocyclohexane

[Synonym ]:
L6TJ AZ BZ &&trans
(1R,2R)-(-)-1,2-Diaminocyclohexane
1,2-Cyclohexanediamine, (1R,2R)-
(-)-R,R-1,2-Diaminocyclohexane
(+/-)-Trans-1,2-Diaminocyclohexane
(1R,2R)-1,2-Cyclohexanediamine
(1R,2R)-cyclohexane-1,2-diamine
(R,R)-1,2-diaminocyclohexane
trans-1,2-Cyclohexanediamine
MFCD00063747
trans-Cyclohexane-1,2-diamine
trans-1,2-Diaminocyclohexane

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
193.6±0.0 °C at 760 mmHg

[ Melting Point ]:
14-15ºC

[ Molecular Formula ]:
C6H14N2

[ Molecular Weight ]:
114.19

[ Flash Point ]:
75.0±0.0 °C

[ Exact Mass ]:
114.115700

[ PSA ]:
52.04000

[ LogP ]:
-0.12

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.484

[ Water Solubility ]:
Soluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2735

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • trans-1,2-dinitrocyclohexane
  • 7-Aza-bicyclo[4.1.0]heptane
  • 1-nitrocyclohex-1-ene
  • m-Phenylenediamine
  • Cyclohexene
  • Nioxime
  • (R)-2-Aminocyclohenanol
  • (NE)-N-[(3E)-3-hydroxyiminocyclohexylidene]hydroxylamine

DownStream

  • 1-N,2-N-bis(7-chloroquinolin-4-yl)cyclohexane-1,2-diamine
  • (1R,2R)-(-)-1,2-Diaminocyclohexane
  • (1S,2S)-(+)-1,2-Diaminocyclohexane
  • dimethyl 3,3'-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanediyl))bis(3-oxopropanoate)
  • trans(−)-DDCP
  • Cyclohexane-1,2-diaminetetraacetic acid

Customs

[ HS Code ]: 2942000000

Articles

Steric modifications tune the regioselectivity of the alkane oxidation catalyzed by non-heme iron complexes.

Inorg. Chem. 50(24) , 12651-60, (2011)

Iron complexes with the tetradentate N-donor ligand N,N'-di(phenylmethyl)-N,N'-bis(2-pyridinylmethyl)-1,2-cyclohexanediamine (bbpc) are reported. Despite the benzyl groups present on the amines, the i...

Antitumor platinum(II) complexes of N-monoalkyl-1R, 2R-diaminocyclohexane derivatives with alkyl groups as hindrance.

J. Inorg. Biochem. 112 , 68-76, (2012)

A number of platinum (II) complexes, characteristic of (1R,2R)-N(1)-alkyl-1,2-diaminocyclohexane derivatives as carrier ligands, were designed, synthesized and characterized, where the alkyl group ser...

Synthesis, in vitro cytotoxicity, and interaction with DNA of platinum(II) complexes with N-monocycloalkyl derivatives of 1R,2R-diaminocyclohexane as carrier ligands.

ChemMedChem 7(4) , 642-9, (2012)

A series of platinum(II) complexes with N-monocyclopentyl/cyclohexyl derivatives of 1R,2R-diaminocyclohexane as carrier ligands and dicarboxylate anions as leaving groups were synthesized and characte...


More Articles

Related Compounds

  • (R,R)-(-)-1,2-diaminocyclohexane monohydrochloride
  • {Pt(trans-(R,R-1,2-diaminocyclohexane))(ascorbate-C(2),O(5))}*3H2O
  • {Pt(trans-(R,R-1,2-diaminocyclohexane))(ascorbato-C(2),O(5))}methanesulfonate
  • {PtCl(dimethyl sulfoxide) (R,R-1,2-diaminocyclohexane)}NO3
  • (1R,2R)-1,2-Dimethyl-cyclohexane
  • Platinum, (1,2-cyclohexanediamine-N,N)bis(D-gluconato-O1)-, [SP-4-2-(1R-trans)]-
  • tert-butyl N-[3-(1-amino-2-methylpropan-2-yl)phenyl]carbamate
  • tert-butyl N-[4-(1-aminocyclobutyl)-3-chlorophenyl]carbamate
  • tert-butyl N-[1-(1-amino-2,2,2-trifluoroethyl)cyclopentyl]carbamate
  • methyl 4-(2-aminopropanoyl)-1-methyl-1H-pyrazole-3-carboxylate
  • Methyl 5-[1-(2-aminopropan-2-yl)cyclopropyl]furan-2-carboxylate
  • 1-{1-[(Tert-butoxy)carbonyl]piperidin-2-yl}-4,4-difluorocyclohexane-1-carboxylic acid
  • 2-(1-Ethylcyclobutoxy)acetic acid
  • Tert-butyl 2-[3-(dimethylamino)phenyl]piperazine-1-carboxylate
  • Methyl 2-amino-3-(3-chloropyridin-4-yl)-3-methylbutanoate
  • tert-butyl N-[2-amino-2-(2-cyclopropyl-1,3-thiazol-4-yl)ethyl]carbamate
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