2-Sulfanylphenol

Names

[ Name ]:
2-Sulfanylphenol

[Synonym ]:
EINECS 214-326-8
2-Mercaptophenol
2-Hydroxythiophenol
2-Sulfanylphenol
MFCD00040447
2-Hydroxybenzenethiol
Phenol, 2-mercapto-

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
223.7±23.0 °C at 760 mmHg

[ Melting Point ]:
20 °C

[ Molecular Formula ]:
C₆H₆OS

[ Molecular Weight ]:
126.176

[ Flash Point ]:
89.1±22.6 °C

[ Exact Mass ]:
126.013931

[ PSA ]:
59.03000

[ LogP ]:
1.56

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.642

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;T: Toxic;

[ Risk Phrases ]:
R23/24/25;R36/38

[ Safety Phrases ]:
S23-S36/37/39-S45-S26

[ RIDADR ]:
2810

[ RTECS ]:
SL7375000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,3-benzoxathiol-2-one
(2-ethoxyphenyl)(methyl)sulfane
DL-2-Bromohexanoic acid
1,3-benzoxathiole-2-thione
2-hydroxy-Benzenediazonium
1,2-Benzenediol
2-(2-pyridinylsulfinyl)phenyl acetate
2-Aminothiophenol
Phenol
2-Methoxy thioanisole

DownStream

2-[4-(2-hydroxyphenyl)sulfanylbutylsulfanyl]phenol
(2,3-DIHYDRO-BENZO[1,4]OXATHIIN-2-YL)-ACETIC ACID METHYL ESTER
acetic acid,2-heptylsulfanylphenol
2-hept-2-ynylsulfanylphenol
2-octylsulfanylphenol
2-(Butylthio)phenol
spiro[1,3-benzoxathiole-2,1'-cyclohexane]
2-(METHYLSULFONYL)PHENOL
Phenoxathiine
2-(Methylsulfinyl)phenol

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

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Nat. Commun. 6 , 5794, (2015)

Early T-cell precursor leukaemia (ETP-ALL) is a high-risk subtype of human leukaemia that is poorly understood at the molecular level. Here we report translocations targeting the zinc finger E-box-bin...

Speciation analysis of mercury in sediments, zoobenthos and river water samples by high-performance liquid chromatography hyphenated to atomic fluorescence spectrometry following preconcentration by solid phase extraction.

Anal. Chim. Acta 615(2) , 115-23, (2008)

A high-pressure microwave digestion was applied for microwave-assisted extraction (MAE) of mercury species from sediments and zoobenthos samples. A mixture containing 3molL(-1) HCl, 50% aqueous methan...

Vanadium(IV) Complexes with Mixed O,S Donor Ligands. Syntheses, Structures, and Properties of the Anions Tris(2-mercapto-4-methylphenolato)vanadate(IV) and Bis(2-mercaptophenolato)oxovanadate(IV).

Inorg. Chem. 35(2) , 347-356, (1996)

Reaction of VO(acac)(2) with 2-mercaptophenol (mpH(2)) in the presence of triethylamine gives the mononuclear tris complex (Et(3)NH)(2)[V(mp)(3)] (1), in which the vanadyl oxygen has been displaced. A...