Nitrocyclohexane

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Names

[ CAS No. ]:
1122-60-7

[ Name ]:
Nitrocyclohexane

[Synonym ]:
Cyclohexane, nitro-
Nitrocyclohexane
MFCD00003843
EINECS 214-354-0

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
202.8±7.0 °C at 760 mmHg

[ Melting Point ]:
-34ºC(lit.)

[ Molecular Formula ]:
C6H11NO2

[ Molecular Weight ]:
129.157

[ Flash Point ]:
74.4±0.0 °C

[ Exact Mass ]:
129.078979

[ PSA ]:
45.82000

[ LogP ]:
1.86

[ Vapour density ]:
4.46 (vs air)

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.465

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GV6600000
CHEMICAL NAME :
Cyclohexane, nitro-
CAS REGISTRY NUMBER :
1122-60-7
BEILSTEIN REFERENCE NO. :
0907243
LAST UPDATED :
199712
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C6-H11-N-O2
MOLECULAR WEIGHT :
129.18
WISWESSER LINE NOTATION :
L6TJ ANW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 26(5),9,1961
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
172 ppm/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Gastrointestinal - hypermotility, diarrhea Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 15(Suppl 1),S28,1996
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
120 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 1,85,1961
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7 mg/m3/2H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle contraction or spasticity
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 1,85,1961
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 26(5),9,1961 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4 mg/m3/3H/31W-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Vascular - BP lowering not characterized in autonomic section Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 1,85,1961
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
273 mg/kg/26W-I
TOXIC EFFECTS :
Gastrointestinal - other changes Liver - liver function tests impaired Liver - other changes
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 26(5),9,1961

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H315-H319-H331-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S26;S45;S36/S37/S39

[ RIDADR ]:
UN 3382 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
GV6600000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2904209090

Synthetic Route

Precursor & DownStream

Precursor

  • cyclohexane
  • Cyclohexane, azido-
  • 1-nitrocyclohex-1-ene
  • Cyclohexylamine
  • carbon monoxide
  • Cyclohexane, iodo-
  • Bromocyclohexane
  • nitrobenzene
  • 1-bromo-1-nitrosocyclohexane
  • 1-methyl-4-(1-nitrocyclohexyl)sulfonylbenzene

DownStream

  • (1-Aminocyclohexyl)methanol
  • Cyclohexanone
  • Cyclohexanone oxime
  • Cyclohexylamine
  • 1-chloro-1-nitro-cyclohexane
  • N-Cyclohexylcyclohexylideneamine
  • 1-nitro-1-(1-nitrocyclohexyl)cyclohexane
  • Dicyclohexylamine
  • (1-nitrocyclohexyl) thiocyanate
  • 2-cyclohexylidenecyclohexanone

Customs

[ HS Code ]: 2904209090

[ Summary ]:
2904209090 derivatives containing only nitro or only nitroso groups。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%


Related Compounds

  • lithium,nitrocyclohexane
  • 2-methylnitrocyclohexane
  • lithium nitrocyclohexane
  • 1-iodo-1-nitrocyclohexane
  • gem-bromonitrocyclohexane
  • 1-ethyl-2-nitrocyclohexane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-(3-Chloro-2,4-difluorophenyl)-3,3-difluoropropan-1-amine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1-(5-Chloropentanoyl)pyrrolidine-3-sulfonyl fluoride
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine