(+)-Diisopinocampheyl chloroborane

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Names

[ CAS No. ]:
112246-73-8

[ Name ]:
(+)-Diisopinocampheyl chloroborane

[Synonym ]:
Chloro[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl][(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane
MFCD00074808
Borane, chloro[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl][(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-
(+)-B-ChlorodiisopinocaMpheylborane
(+)-Diisopinocampheyl Chloroborane
(+)-Diisopinocampheylchloroborane

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
369.6±25.0 °C at 760 mmHg

[ Melting Point ]:
53-55 °C(lit.)

[ Molecular Formula ]:
C20H34BCl

[ Molecular Weight ]:
320.748

[ Flash Point ]:
177.3±23.2 °C

[ Exact Mass ]:
320.244202

[ LogP ]:
7.98

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.501

[ Storage condition ]:
2-8°C

[ Stability ]:
(+)-二异松蒎基氯硼烷(112246-73-8)对水较敏感, 极易与空气中或溶剂中的水分反映生成氯化氢。受到空气中氧气氧化作用使其对酮的还原性降低。

MSDS

Safety Information

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34;R37

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

Synthetic Route

Precursor & DownStream

Precursor

  • (1S)-(-)-Alpha-Pinene
  • Diisopinocampheylborane
  • Alpha-pinene

DownStream

  • (+)-Ipc2B(allyl), 1M in dioxane

Related Compounds

  • (-)-Diisopinocampheyl Chloroborane
  • (+/-)-4-(2-furyl)-butan-2-ol acetate
  • (+)-limousamine
  • (+)-(1R)-4-methyl-3-cyclohexen-1-yl 4-methylbenzenesulfonate
  • (+/-)-(N-carboxymethyl)aspartic acid
  • (+/-)S-2-(4-methoxyphenyl)-1-(phenylsulfinyl)ethene