m-Carbomethoxybenzyl bromide

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Names

[ CAS No. ]:
1129-28-8

[ Name ]:
m-Carbomethoxybenzyl bromide

[Synonym ]:
3-MeO2CC6H4CH2Br
m-Carbomethoxybenzyl bromide
Methyl 3-(bromomethyl)benzoate
Methyl 3-bromomethylbenzoate
3-CO2Me-C6H4CH2Br
3-carbomethoxybenzyl bromide
MFCD00051437
α-Bromo-m-toluic Acid Methyl Ester
Methyl α-Bromo-m-toluate
3-(Bromomethyl)benzoic acid methyl ester
Benzoic acid, 3-(bromomethyl)-, methyl ester
3-methoxycarbonylbenzyl bromide
E1R CVO1
EINECS 419-100-4

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
288.7±23.0 °C at 760 mmHg

[ Melting Point ]:
46-47 °C(lit.)

[ Molecular Formula ]:
C9H9BrO2

[ Molecular Weight ]:
229.071

[ Flash Point ]:
128.4±22.6 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
2.90

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.560

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314-H317

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl 3-methylbenzoate
  • Methyl (3-hydroxymethyl)benzoate
  • Methanol
  • 3-(bromomethyl)benzoyl chloride
  • 3-(bromomethyl)benzoicacid
  • 3-Methylbenzoylchloride
  • Mono-methyl isophthalate
  • 3-Methylbenzoic acid
  • Isophthalic acid
  • Dimethyl isophthalate

DownStream

  • METHYL 3-(1-PYRROLIDYLMETHYL)BENZOATE
  • 3-(Cyanomethyl)benzoic acid
  • methyl 3-(piperazin-1-ylmethyl)benzoate
  • 3-(Carboxymethyl)benzoic acid
  • Methyl 3-(((tert-butoxycarbonyl)amino)methyl)benzoate
  • 3-(hydroxymethyl)benzoic acid
  • Methyl 3-methylbenzoate
  • methyl 3-(aminomethyl)benzoate
  • tert-Butyl 3-(hydroxymethyl)benzylcarbamate
  • 3-MORPHOLIN-4-YLMETHYLBENZOIC ACID

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • {[(8E)-10-Ethoxy-10-oxo-8-decen-1-yl]sulfanyl}(imino)methanaminiu m bromide
  • methyl 5-(bromomethyl)-2-fluorobenzoate
  • m-PEG8-bromide
  • m-cyanobenzyl bromide
  • M-BROMOBENZOYL BROMIDE
  • m-tolylmagnesium bromide
  • (2E)-1-(2-chlorophenyl)-3-(dimethylamino)prop-2-en-1-one
  • 2-Benzyloxycarbonylamino-2-(3-thienyl)acetic acid
  • Ethyl 2-bromo-6-propyl-4-pyridinecarboxylate
  • Ethyl 4-(3-Hydroxy-1-propyn-1-yl)benzoate
  • Methyl 2-(chlorosulfonyl)nicotinate
  • 3-Amino-4-butyramido-5-methylbenzoic acid
  • 10-(Aminomethyl)[1]benzopyrano[4,3,2-de]phthalazin-3(2H)-one
  • 4-({3-[2-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)ethyl]-2,4-dioxo-1,3-thiazolidin-5-yl}amino)benzoic acid
  • 1-(3,4-dimethylphenyl)-4-isopropyl-6-(2-morpholino-2-oxoethyl)-1H-pyrazolo[3,4-d]pyridazin-7(6H)-one
  • 1-(3,4-dimethylphenyl)-6-[2-(4-methylpiperidin-1-yl)-2-oxoethyl]-4-(propan-2-yl)-1H,6H,7H-pyrazolo[3,4-d]pyridazin-7-one
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