m-Carbomethoxybenzyl bromide

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Names

[ CAS No. ]:
1129-28-8

[ Name ]:
m-Carbomethoxybenzyl bromide

[Synonym ]:
3-MeO2CC6H4CH2Br
m-Carbomethoxybenzyl bromide
Methyl 3-(bromomethyl)benzoate
Methyl 3-bromomethylbenzoate
3-CO2Me-C6H4CH2Br
3-carbomethoxybenzyl bromide
MFCD00051437
α-Bromo-m-toluic Acid Methyl Ester
Methyl α-Bromo-m-toluate
3-(Bromomethyl)benzoic acid methyl ester
Benzoic acid, 3-(bromomethyl)-, methyl ester
3-methoxycarbonylbenzyl bromide
E1R CVO1
EINECS 419-100-4

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
288.7±23.0 °C at 760 mmHg

[ Melting Point ]:
46-47 °C(lit.)

[ Molecular Formula ]:
C9H9BrO2

[ Molecular Weight ]:
229.071

[ Flash Point ]:
128.4±22.6 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
2.90

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.560

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314-H317

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl 3-methylbenzoate
  • Methyl (3-hydroxymethyl)benzoate
  • Methanol
  • 3-(bromomethyl)benzoyl chloride
  • 3-(bromomethyl)benzoicacid
  • 3-Methylbenzoylchloride
  • Mono-methyl isophthalate
  • 3-Methylbenzoic acid
  • Isophthalic acid
  • Dimethyl isophthalate

DownStream

  • METHYL 3-(1-PYRROLIDYLMETHYL)BENZOATE
  • 3-(Cyanomethyl)benzoic acid
  • methyl 3-(piperazin-1-ylmethyl)benzoate
  • 3-(Carboxymethyl)benzoic acid
  • Methyl 3-(((tert-butoxycarbonyl)amino)methyl)benzoate
  • 3-(hydroxymethyl)benzoic acid
  • Methyl 3-methylbenzoate
  • methyl 3-(aminomethyl)benzoate
  • tert-Butyl 3-(hydroxymethyl)benzylcarbamate
  • 3-MORPHOLIN-4-YLMETHYLBENZOIC ACID

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • {[(8E)-10-Ethoxy-10-oxo-8-decen-1-yl]sulfanyl}(imino)methanaminiu m bromide
  • methyl 5-(bromomethyl)-2-fluorobenzoate
  • m-PEG8-bromide
  • m-cyanobenzyl bromide
  • M-BROMOBENZOYL BROMIDE
  • m-tolylmagnesium bromide
  • 2-(6-{[(Tert-butoxy)carbonyl]amino}-7-methyl-2-oxabicyclo[3.2.0]heptan-6-yl)acetic acid
  • (3S)-3-{[(1rs,4rs)-4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclohexyl]formamido}butanoic acid
  • 1-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanoyl]-3-hydroxyazetidine-3-carboxylic acid
  • (3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(2-methylcyclohexyl)propanoic acid
  • N-tert-butyl-1-[6-(trifluoromethyl)pyrimidin-4-yl]azetidine-3-carboxamide
  • rac-2-[(1R,5S)-2-aminobicyclo[3.1.0]hexan-2-yl]acetic acid
  • 2-[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)spiro[3.4]octan-1-yl]acetic acid
  • Tert-butyl 3-amino-3-(carbamoylmethyl)-8-azabicyclo[3.2.1]octane-8-carboxylate
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(1,2-thiazol-4-yl)propanoic acid
  • tert-butyl N-[(3S)-2-amino-1-(4-chloro-3-methylphenyl)pentan-3-yl]carbamate