(2R)-(-)-Glycidyl tosylate

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Names

[ Name ]:
(2R)-(-)-Glycidyl tosylate

[Synonym ]:
2-Oxiranemethanol, 4-methylbenzenesulfonate, (2R)-
2-Oxiranemethanol, 4-methylbenzenesulfonate, (2S)-
(2R)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
(2R)-(−)-Glycidyl tosylate
[(2R)-oxiran-2-yl]methyl 4-methylbenzenesulfonate
(2R)-(-)-Glycidyl p-Toluenesulfonate
(R)-(−)-Glycidyl p-toluenesulfonate
(2R)-2-Oxiranylmethyl 4-methylbenzenesulfonate
MFCD00010834
(R)-(-)-Glycidyltosylate
(-)-Glycidyl tosylate
Oxiranemethanol, 4-methylbenzenesulfonate, (R)-
(2S)-2-Oxiranylmethyl 4-methylbenzenesulfonate
(R)-(−)-Oxirane-2-methanol p-toluenesulfonate
(2R)-Oxiran-2-ylmethyl-4-methylbenzolsulfonat
(R)-oxiran-2-ylmethyl 4-methylbenzenesulfonate
(R)-(−)-Glycidyl tosylate
EINECS 205-970-0
(2S)-Oxiran-2-ylmethyl-4-methylbenzolsulfonat
(R)-(−)-Oxirane-2-methanol p-toluenesulfonate salt
(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
(2R)-(-)-Glycidyl tosylate
T3OTJ B1OSWR D1 &&S Form
(2S)-Glycidyl tosylate
(R)-Glycidyl tosylate
p-Toluenesulfonic Acid (2R)-(-)-Glycidyl Ester
(S)-Glycidyl tosylate
(R)-(-)-Glycidyl tosylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
370.5±15.0 °C at 760 mmHg

[ Melting Point ]:
46-49 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₂O₄S

[ Molecular Weight ]:
228.265

[ Flash Point ]:
177.9±20.4 °C

[ Exact Mass ]:
228.045624

[ PSA ]:
64.28000

[ LogP ]:
1.35

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.550

[ Water Solubility ]:
decomposes

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RR0510000

CHEMICAL NAME :: Oxiranemethanol, 4-methylbenzenesulfonate, (R)-

CAS REGISTRY NUMBER :: 113826-06-5

BEILSTEIN REFERENCE NO. :: 3592142

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C10-H12-O4-S

MOLECULAR WEIGHT :: 228.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

Safety Information

[ Symbol ]:

GHS05, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H318-H334-H350

[ Precautionary Statements ]:
P201-P261-P280-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R45;R41;R43;R51/53;R68

[ Safety Phrases ]:
S61-S45-S36/37/39-S26-S53

[ RIDADR ]:
UN 3077 9/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
RR0510000

[ Hazard Class ]:
9.0

[ HS Code ]:
29109000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Tosyl chloride
(±)-Glycidol
(2S)-3-Chlorpropan-1,2-diol
dichloroethane
Allyl alcohol

DownStream

(R)-(-)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
(S)-(+)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
phenyl glycidyl ether
(R)-2-(3-CHLORO-4-METHANESULFONYLPHENYL)-3-(2-OXOCYCLOPENTYL)PROPIONICACID
(S)-2-((4-(2-METHOXYETHYL)PHENOXY)METHYL) OXIRANE
(S)-2-((4-NITROPHENOXY)METHYL)OXIRANE
(R)-2-((4-NITROPHENOXY)METHYL)OXIRANE
(S)-4-(OXIRAN-2-YLMETHOXY)BENZONITRILE
Benzeneethanol, a-(phenylmethyl)-

Customs

[ HS Code ]: 29109000

Articles

Henry, N. et al.

Tetrahedron Lett. 45 , 1465, (2004)

(2R)-glycidyl 4-chlorobenzenesulfonate
(2R)-glycidyl 4-chloro-3-nitrobenzenesulfonate
(S)-Glycidyl tosylate
glycidyl 4-toluenesulfonate
(2-PYRIDIN-3-YL-1,3-THIAZOL-4-YL)ACETICACID
oxiran-2-ylmethyl 4-methyl-1-benzenesulfonate
13-Ethyl-8-(4-ethylphenyl)-5-oxa-2,11,13-triazatricyclo[7.4.0.0^{3,7}]trideca-1(9),3(7)-diene-6,10,12-trione
13-Methyl-8-phenyl-5-oxa-2,11,13-triazatricyclo[7.4.0.0^{3,7}]trideca-1(9),3(7)-diene-6,10,12-trione
[(3-Carbamoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)carbamoyl]methyl 5,6-dichloropyridine-3-carboxylate
4-(3-Aminoprop-1-en-1-yl)benzonitrile
2-[(4-piperidinylmethyl)amino]Ethanol
2-[(6-amino-4-imino-1,4-dihydropyrimidin-2-yl)sulfanyl]-N-(1-cyano-1,2-dimethylpropyl)acetamide
2-[3-chloro-2-oxo-5-(trifluoromethyl)-1,2-dihydropyridin-1-yl]-N-(1-cyano-1,2-dimethylpropyl)acetamide
2-Amino-4-[1-cyano-2-(4-methylphenyl)ethyl]-6-[ethyl(2-methyl-2-propen-1-yl)amino]-3,5-pyridinedicarbonitrile
N-(6-methoxypyridin-3-yl)-2-[2-(4-methylphenyl)ethenesulfonamido]acetamide
N-[(4-methoxyphenyl)methyl]-2-(2-methoxy-N-thiophen-2-ylsulfonylanilino)acetamide

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