Tetrapropylammonium perruthenate

[ Melting Point ]:
160ºC

[ Molecular Formula ]:
C₁₂H₂₈NO₄Ru

[ Molecular Weight ]:
351.425

[ Exact Mass ]:
352.106232

[ PSA ]:
74.27000

[ LogP ]:
2.96800

[ Appearance of Characters ]:
crystal | green

[ Storage condition ]:
2-8°C

[ Stability ]:
store cold

[ Water Solubility ]:
Insoluble in water.

Click to get detail MSDS

[ Symbol ]:

GHS03, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H272-H315-H319-H335

[ Precautionary Statements ]:
P220-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
O: Oxidizing agent;Xi: Irritant;

[ Risk Phrases ]:
R36/37/38;R5;R8

[ Safety Phrases ]:
S17-S26-S36

[ RIDADR ]:
UN 1479 5.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
5.1

[ HS Code ]:
2923900090

Precursor

DownStream

[ HS Code ]: 2923900090

[ Summary ]:
2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Oxidation of hydroxyl-substituted organotrifluoroborates.

J. Am. Chem. Soc. 128 , 9634, (2006)

Potassium- and tetra-n-butylammonium organotrifluoroborates containing hydroxyl groups have been prepared and oxidized using several common oxidants. Aryl-, alkenyl-, and alkyltrifluoroborates contain...

A double donor-activated ruthenium(VII) catalyst: synthesis of enantiomerically pure THF-diols.

Angew. Chem. Int. Ed. Engl. 49(9) , 1587-90, (2010)

Single-flask synthesis of N-acylated indoles by catalytic dehydrogenative coupling with primary alcohols.

Org. Lett. 11(7) , 1651-4, (2009)

Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild condition...

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