2-Methyl-3-buten-2-ol
Suppliers
Names
[ CAS No. ]:
115-18-4
[ Name ]:
2-Methyl-3-buten-2-ol
[Synonym ]:
3-Buten-2-ol, 2-methyl-
2-Methyl-3-buten-2-ol
3-hydroxy-3-methylbut-1-ene
3-Hydroxy-3-methyl-1-butene
MFCD00004470
1,1-Dimethylallyl alcohol,3-Hydroxy-3-methyl-1-butene
3-hydroxy-3-methylbutene
EINECS 204-068-4
2-methylbut-3-en-2-ol
Chemical & Physical Properties
[ Density]:
0.8±0.1 g/cm3
[ Boiling Point ]:
98.5±0.0 °C at 760 mmHg
[ Melting Point ]:
-43 °C
[ Molecular Formula ]:
C5H10O
[ Molecular Weight ]:
86.132
[ Flash Point ]:
13.3±0.0 °C
[ Exact Mass ]:
86.073166
[ PSA ]:
20.23000
[ LogP ]:
0.87
[ Vapour Pressure ]:
22.9±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.424
[ Storage condition ]:
Flammables area
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EM9472000
- CHEMICAL NAME :
- 1-Buten-3-ol, 3-methyl-
- CAS REGISTRY NUMBER :
- 115-18-4
- BEILSTEIN REFERENCE NO. :
- 1698263
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 6
- MOLECULAR FORMULA :
- C5-H10-O
- MOLECULAR WEIGHT :
- 86.15
- WISWESSER LINE NOTATION :
- QXI&I&IUI
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1315 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PLMEAA Planta Medica. (Georg Thieme Verlag, Postfach 732, D-7000 Stuttgart 1, Fed. Rep. Ger.) V.1- 1953- Volume(issue)/page/year: 48,120,1983
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- IJSBDB Indian Journal of Chemistry, Section B: Organic Chemistry, Including Medicinal Chemistry. (Publications & Information Directorate, Council of Scientific and Industrial Research (CSIR), Hillside Rd., New Delhi 110 012, India) V.14B- 1976- Volume(issue)/page/year: 14,449,1976
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1680 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 5,161,1955
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 435 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(5),61,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7945 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 1557 (estimated) No. of Female Employees: 276 (estimated)
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H302-H315-H319
[ Precautionary Statements ]:
P210-P280-P301 + P312 + P330-P305 + P351 + P338-P337 + P313-P403 + P235
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F+:Extremely flammable
[ Risk Phrases ]:
R11
[ Safety Phrases ]:
S16-S26-S36
[ RIDADR ]:
UN 1987 3/PG 2
[ WGK Germany ]:
1
[ RTECS ]:
EM9472000
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
29052990
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2905290000
[ Summary ]:
2905290000 unsaturated monohydric alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
Articles
J. Phys. Chem. A 114(12) , 4224-31, (2010)
The gas-phase reactions of Cl atoms with allyl alcohol (k(1)), 3-buten-2-ol (k(2)), and 2-methyl-3-buten-2-ol (k(3)) at 296 +/- 2 K have been investigated using absolute and relative rate methods in 1...
J. Chem. Ecol. 27(12) , 2425-35, (2001)
Responses of the European spruce bark beetle, 1. typographus (Coleoptera: Scolytidae), to low release-rate pheromones were investigated in two experiments in a spruce forest at Wellin, southern Belgiu...
Phys. Chem. Chem. Phys. 13(6) , 2069-75, (2011)
Multiphase acid-catalyzed oxidation with hydrogen peroxide (H(2)O(2)) has been suggested recently to be a potential route to SOA formation from isoprene and its gas-phase oxidation products, the kinet...