(Bromodifluoromethyl)trimethylsilane

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Names

[ CAS No. ]:
115262-01-6

[ Name ]:
(Bromodifluoromethyl)trimethylsilane

[Synonym ]:
[Bromo(difluoro)methyl](trimethyl)silane
Bromodifluoro(trimethylsilyl)methane

Chemical & Physical Properties

[ Density]:
1.306

[ Boiling Point ]:
108°C(lit.)

[ Molecular Formula ]:
C4H9BrF2Si

[ Molecular Weight ]:
203.10100

[ Flash Point ]:
46℃

[ Exact Mass ]:
201.96200

[ LogP ]:
3.27140

[ Index of Refraction ]:
n/D1.407

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P210-P305 + P351 + P338-P370 + P378

[ Safety Phrases ]:
24/25

[ RIDADR ]:
UN 1993C 3 / PGIII

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (Difluoromethyl)(trimethyl)silane
  • Bromo(trimethyl)silane
  • Dibromodifluoromethane
  • (Trifluoromethyl)trimethylsilane
  • Chlorotrimethylsilane
  • bromochlorodifluoromethane

DownStream

  • 4-(DIFLUOROMETHYLTHIO)NITROBENZENE
  • 1-(4-(Difluoromethoxy)phenyl)ethanone
  • 4-(Difluoromethoxy)benzaldehyde
  • 2-(Difluoromethoxy)benzaldehyde
  • (Difluoromethyl)(trimethyl)silane
  • 4-(difluoromethoxy)benzyl alcohol
  • Benzene,(3,3-difluoro-1-cyclopropen-1-yl)-(9CI)
  • 3,3-difluoro-1-octylcyclopropene
  • [(Difluoromethyl)sulfonyl]benzene
  • 1-(Difluoromethoxy)-2-nitrobenzene

Articles

Coupling of a,a-difluoro-substituted organozinc reagents with 1-bromoalkynes. Zemtsov AA, et al.

Beilstein J. Org. Chem. 11(1) , 2145-2149, (2015)

Recent advances in the synthetic application of difluorocarbene. Ni C and Hu J.

Synthesis 46(07) , 842-863, (2014)

Synthesis of gem-Difluorocyclopropa (e) nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br. Li L, et al.

Angew. Chem. Int. Ed. Engl. 52(47) , 12390-12394, (2013)


More Articles

Related Compounds

  • (bromodifluoromethyl)(heptyl)sulfane
  • bromodifluoromethyl(1+)
  • bromodifluoromethyl p-bromophenyl sulfide
  • bromodifluoromethyl phenyl selenide
  • (bromodifluoromethyl)tri-p-tolylphosphonium bromide
  • BroModifluoroMethyl phenyl sulfone
  • Tert-butyl 3-(cyanomethyl)-5-(trifluoromethyl)benzoate
  • 3-[(1,3-Thiazol-2-yloxy)methyl]-1-[3-(trifluoromethyl)-[1,2,4]triazolo[4,3-b]pyridazin-6-yl]piperidine
  • 6-{4-[2-Oxo-1-(2,2,2-trifluoroethyl)pyrrolidin-3-yl]piperazin-1-yl}-2-(propan-2-yl)-2,3-dihydropyridazin-3-one
  • 2-[4-(5-Bromopyridin-2-yl)piperazin-1-yl]-1-(morpholin-4-yl)ethan-1-one
  • 3-[4-(4-Chlorophenyl)-4-hydroxypiperidin-1-yl]-1-cyclopropylpyrrolidin-2-one
  • 4-(4-Chlorophenyl)-1-[(1,4-dioxan-2-yl)methyl]piperidin-4-ol
  • 2-methyl-4-(3-methyl-1,2,4-thiadiazol-5-yl)-1-[(1-methyl-1H-pyrazol-4-yl)methyl]piperazine
  • 2-({[2-(1-methyl-1H-pyrazol-4-yl)pyridin-4-yl]methyl}amino)pyridine-4-carbonitrile
  • 7-{2-methyl-5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}-3-(trifluoromethyl)-5H,6H,7H,8H-[1,2,4]triazolo[4,3-a]pyrazine
  • 4,5-dimethyl-6-{3-methyl-4-[(1-methyl-1H-pyrazol-4-yl)methyl]piperazin-1-yl}pyrimidine
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