(Bromodifluoromethyl)trimethylsilane

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Names

[ CAS No. ]:
115262-01-6

[ Name ]:
(Bromodifluoromethyl)trimethylsilane

[Synonym ]:
[Bromo(difluoro)methyl](trimethyl)silane
Bromodifluoro(trimethylsilyl)methane

Chemical & Physical Properties

[ Density]:
1.306

[ Boiling Point ]:
108°C(lit.)

[ Molecular Formula ]:
C4H9BrF2Si

[ Molecular Weight ]:
203.10100

[ Flash Point ]:
46℃

[ Exact Mass ]:
201.96200

[ LogP ]:
3.27140

[ Index of Refraction ]:
n/D1.407

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P210-P305 + P351 + P338-P370 + P378

[ Safety Phrases ]:
24/25

[ RIDADR ]:
UN 1993C 3 / PGIII

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (Difluoromethyl)(trimethyl)silane
  • Bromo(trimethyl)silane
  • Dibromodifluoromethane
  • (Trifluoromethyl)trimethylsilane
  • Chlorotrimethylsilane
  • bromochlorodifluoromethane

DownStream

  • 4-(DIFLUOROMETHYLTHIO)NITROBENZENE
  • 1-(4-(Difluoromethoxy)phenyl)ethanone
  • 4-(Difluoromethoxy)benzaldehyde
  • 2-(Difluoromethoxy)benzaldehyde
  • (Difluoromethyl)(trimethyl)silane
  • 4-(difluoromethoxy)benzyl alcohol
  • Benzene,(3,3-difluoro-1-cyclopropen-1-yl)-(9CI)
  • 3,3-difluoro-1-octylcyclopropene
  • [(Difluoromethyl)sulfonyl]benzene
  • 1-(Difluoromethoxy)-2-nitrobenzene

Articles

Coupling of a,a-difluoro-substituted organozinc reagents with 1-bromoalkynes. Zemtsov AA, et al.

Beilstein J. Org. Chem. 11(1) , 2145-2149, (2015)

Recent advances in the synthetic application of difluorocarbene. Ni C and Hu J.

Synthesis 46(07) , 842-863, (2014)

Synthesis of gem-Difluorocyclopropa (e) nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br. Li L, et al.

Angew. Chem. Int. Ed. Engl. 52(47) , 12390-12394, (2013)


More Articles

Related Compounds

  • (bromodifluoromethyl)(heptyl)sulfane
  • bromodifluoromethyl(1+)
  • bromodifluoromethyl p-bromophenyl sulfide
  • bromodifluoromethyl phenyl selenide
  • (bromodifluoromethyl)tri-p-tolylphosphonium bromide
  • BroModifluoroMethyl phenyl sulfone
  • 1-methyl-2-[2-(1H-pyrazol-1-yl)ethyl]piperazine
  • 1-[1-(3-tert-butyl-1-methyl-1H-pyrazol-4-yl)cyclopropyl]ethan-1-amine
  • 1-methyl-5-[(2R)-oxiran-2-yl]-1H-1,2,3-triazole
  • 5-(Thiophen-3-yl)-1-oxa-8-thia-4-azaspiro[5.5]undecane
  • rel-((1R,3S)-3-(((tert-Butyldiphenylsilyl)oxy)methyl)-2,2-dimethylcyclopropyl)methanol
  • (1R)-2-amino-1-(2-methyl-2,3-dihydro-1-benzofuran-5-yl)ethan-1-ol
  • Methyl 5-(2-aminoacetyl)-2-methylfuran-3-carboxylate
  • [2-(1-methyl-4-nitro-1H-pyrazol-5-yl)cyclopropyl]methanamine
  • tert-Butyl (3aS,4R,7S,8aR)-2-oxooctahydro-2H-4,7-epiminocyclohepta[d]oxazole-9-carboxylate
  • 2-[(1R)-3-amino-1-hydroxypropyl]-4-nitrophenol
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