2-methyoxypropene

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Names

[ CAS No. ]:
116-11-0

[ Name ]:
2-methyoxypropene

[Synonym ]:
2-Methoxyprop-1-ene
MFCD00014929
2-methyoxypropene
2-Methoxy-1-propene
Isopropenyl Methyl Ether
EINECS 204-125-3
2-Methoxyprop-1-en
Methyl prop-1-en-2-yl ether
1-Propene, 2-methoxy-

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
32.0±9.0 °C at 760 mmHg

[ Melting Point ]:
< 25ºC

[ Molecular Formula ]:
C4H8O

[ Molecular Weight ]:
72.106

[ Flash Point ]:
-29.4±0.0 °C

[ Exact Mass ]:
72.057518

[ PSA ]:
9.23000

[ LogP ]:
1.06

[ Vapour Pressure ]:
590.8±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.374

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
negligible

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UD0800000
CHEMICAL NAME :
1-Propene, 2-methoxy-
CAS REGISTRY NUMBER :
116-11-0
BEILSTEIN REFERENCE NO. :
1734635
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-H8-O
MOLECULAR WEIGHT :
72.12
WISWESSER LINE NOTATION :
1YO1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1870 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
64000 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>20 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H302

[ Supplemental HS ]:
May form explosive peroxides.

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F+:Highlyflammable;Xn:Harmful;

[ Risk Phrases ]:
R12;R19;R22

[ Safety Phrases ]:
S3-S16-S29-S33-S7/9-S9-S18

[ RIDADR ]:
UN 1993 3/PG 1

[ WGK Germany ]:
1

[ RTECS ]:
UD0800000

[ Packaging Group ]:
I

[ Hazard Class ]:
3

[ HS Code ]:
2909199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Allene
  • Propyne
  • Methanol
  • 2,2-Dimethoxypropane
  • Carbon dioxide
  • Methyl bromide
  • 1-methylvinyl oxide ion
  • Pyridine
  • tert-butyl 2,2,3,3,4,4,4-heptafluorobutaneperoxoate
  • Acetone

DownStream

  • 4-Methyl 3-(2-methyl-2-propanyl) (4S,5R)-2,2,5-trimethyl-1,3-oxaz olidine-3,4-dicarboxylate
  • (R)-2-(AMINOETHYL)-1-N-BOC-PYRROLIDINE
  • (S)-Methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate
  • (-)-Dimethyl 2,3-O-isopropylidene-L-tartrate
  • 2,2,4-trimethyl-1,3-oxathiolan-5-one
  • N-Isopropylaniline
  • N,N-DIISOPROPYLANILINE
  • 2-(ISOPROPYLAMINO)BENZONITRILE
  • 3-(t-Boc)-2,2-dimethyl-4-phenyl-1,3-oxazolidin-5-yl]formic Acid Ethyl Ester
  • 2,2-bis(phenylthio)propane

Customs

[ HS Code ]: 2909199090

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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