Decabromodiphenyl Oxide

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Names

[ CAS No. ]:
1163-19-5

[ Name ]:
Decabromodiphenyl Oxide

[Synonym ]:
FR-10
DECA
br55n
dbdpo
fr300ba
frp53
2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether
1,1’-Oxybis(2,3,4,5,6-Pentabromo-Benzen
DecabroModiphenyl Ether
EINECS 214-604-9
FR-300BA (Deca)
fr300
Pentabromobenzylbromide
BDE-209
PBDE209
de83r
Perbromodiphenyl Ether
6,6'-Oxybis(1,2,3,4,5-pentabromobenzene)
MFCD00000059

Chemical & Physical Properties

[ Density]:
3.0±0.1 g/cm3

[ Boiling Point ]:
425 ºC

[ Melting Point ]:
302.5 ºC

[ Molecular Formula ]:
C12Br10O

[ Molecular Weight ]:
959.168

[ Flash Point ]:
241.4±28.6 °C

[ Exact Mass ]:
949.178223

[ PSA ]:
9.23000

[ LogP ]:
11.24

[ Vapour Pressure ]:
0.0±1.5 mmHg at 25°C

[ Index of Refraction ]:
1.738

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
<0.1 g/100 mL at 20 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KN3525000
CHEMICAL NAME :
Ether, bis(pentabromophenyl)
CAS REGISTRY NUMBER :
1163-19-5
BEILSTEIN REFERENCE NO. :
2188438
LAST UPDATED :
199806
DATA ITEMS CITED :
16
MOLECULAR FORMULA :
C12-Br10-O
MOLECULAR WEIGHT :
959.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0522261 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0522261
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>3 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(8),18,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
24 gm/kg/30D-C
TOXIC EFFECTS :
Liver - other changes Endocrine - thyroid weight (goiter)
REFERENCE :
EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 11,153,1975 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1092 gm/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - tumors
REFERENCE :
NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-309,1986 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
100 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
REFERENCE :
COTODO Journal of Fire and Flammability/Combustion Toxicology Supplement. (Westport, CT) V.1-2, 1974-75. For publisher information, see JCTODH. Volume(issue)/page/year: 1,52,1974 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 48,73,1990 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 48,73,1990 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 3 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4046 No. of Facilities: 981 (estimated) No. of Industries: 12 No. of Occupations: 30 No. of Employees: 32661 (estimated) No. of Female Employees: 8875 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H304-H315-H336-H361d-H373-H410

[ Precautionary Statements ]:
P201-P210-P273-P301 + P310-P331-P370 + P378

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S36/37-S62-S61-S60

[ RIDADR ]:
3152

[ WGK Germany ]:
1

[ RTECS ]:
KN3525000

[ Packaging Group ]:
II

[ Hazard Class ]:
9

[ HS Code ]:
29093031

Synthetic Route

Precursor & DownStream

Precursor

  • Diphenyl oxide
  • Bromine
  • Aluminium bromide

DownStream

  • Ethene,1,1,2,2-tetrabromo-
  • 1,2,3,4,5-Pentabromobenzene
  • PERBROMOBENZENE
  • hexabromo-1,3-butadiene
  • octabromostyrene
  • Diphenyl oxide
  • 1,2,3,4,5-Pentabromo-6-(2,3,5,6-tetrabromophenoxy)benzene
  • nonabromodiphenylether
  • 2,2',3,3',4,4',5,6,6'-nonabde

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

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