Aflatoxin G1

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Names

[ CAS No. ]:
1165-39-5

[ Name ]:
Aflatoxin G1

[Synonym ]:
AF G1
MFCD00005089
Aflatoxin G(1)
1H,12H-Furo[3',2':4,5]furo[2,3-h]pyrano[3,4-c][1]benzopyran-1,12-dione, 3,4,7a,10a-tetrahydro-5-methoxy-, (7aR,10aS)-
aflatoxin g1 solution
AFLATOXIN G
EINECS 214-615-9
Aflatoxin G1,crystalline
(7ar-cis)-10a-tetrahydro-5-methoxy
10a-tetrahydro-5-methoxy
Aflatoxin G1
(7aR,10aS)-5-Methoxy-3,4,7a,10a-tetrahydro-1H,12H-furo[3',2':4,5]furo[2,3-h]pyrano[3,4-c]chromene-1,12-dione

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
612.1±55.0 °C at 760 mmHg

[ Melting Point ]:
244-246ºC

[ Molecular Formula ]:
C17H12O7

[ Molecular Weight ]:
328.273

[ Flash Point ]:
274.1±31.5 °C

[ Exact Mass ]:
328.058289

[ PSA ]:
84.20000

[ LogP ]:
-0.17

[ Vapour Pressure ]:
0.0±1.8 mmHg at 25°C

[ Index of Refraction ]:
1.680

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LV1720000
CAS REGISTRY NUMBER :
1165-39-5
BEILSTEIN REFERENCE NO. :
1299768
LAST UPDATED :
199806
DATA ITEMS CITED :
39
MOLECULAR FORMULA :
C17-H12-O7
MOLECULAR WEIGHT :
328.29

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
14900 ug/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - pleural effusion Liver - jaundice, other or unclassified Endocrine - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
785 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
1 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4100 ug/kg/22W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
12 mg/kg/30W-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
24 mg/kg/20W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8 mg/kg/20W-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5600 ug/kg/2W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors
TYPE OF TEST :
Sperm Morphology
TYPE OF TEST :
DNA adduct

MUTATION DATA

TYPE OF TEST :
Mutation test systems - not otherwise specified
TEST SYSTEM :
Primate - monkey Kidney
DOSE/DURATION :
2 mg/L
REFERENCE :
JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 48,1647,1972 *** REVIEWS *** IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 10,51,1976 IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 56,245,1993 TOXICOLOGY REVIEW LLOYA2 Lloydia. (Cincinnati, OH) V.1-41, 1938-78. For publisher information, see JNPRDF. Volume(issue)/page/year: 38,21,1975 TOXICOLOGY REVIEW BAREA8 Bacteriological Reviews. (Washington, DC) V.1-41, 1937-77. Volume(issue)/page/year: 30,460,1966 TOXICOLOGY REVIEW PMDCAY Progress in Medical Chemistry. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1961- Volume(issue)/page/year: 10,85,1974 TOXICOLOGY REVIEW IJNDAN Indian Journal of Nutrition and Dietetics. (Sri Avinashilingam Home Science College for Women, Coimbatore 641 043, India) V.7- 1970- Volume(issue)/page/year: 8,85,1971

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H304-H315-H319-H340-H350-H372

[ Precautionary Statements ]:
P201-P210-P301 + P310-P305 + P351 + P338-P308 + P313-P331

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T: Toxic;T+: Very toxic;F: Flammable;Xn: Harmful;

[ Risk Phrases ]:
R45

[ Safety Phrases ]:
53-28-36/37-45-62-26-16-7-36

[ RIDADR ]:
UN 3462 6

[ WGK Germany ]:
3

[ RTECS ]:
LV1720000

[ Packaging Group ]:
I

[ Hazard Class ]:
6.1(a)

Synthetic Route

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Related Compounds

  • Aflatoxin G1-d3
  • Aflatoxin G1-13C17
  • Dihydroaflatoxin G1
  • Aflatoxin G1 9,10-oxide
  • Aflatoxin B1-13C17
  • aflatoxin M1 8,9-epoxide
  • N-(cyanomethyl)-N-cyclopropyl-2-{4-[(3,5-dimethyl-1,2-oxazol-4-yl)methoxy]phenyl}acetamide
  • 1-Benzoxepin-5-amine, 2,3,4,5-tetrahydro-6,8-dimethyl-
  • 4-Chloro-N-isobutyl-1H-pyrrole-2-carboxamide
  • 2-(4-Fluoro-3-methylphenyl)-4-methylthiazole-5-carboxylic acid
  • 3-(5-bromothiophen-2-yl)-N-(cyanomethyl)-N-cyclopropylprop-2-enamide
  • 3,6-dichloro-N-(cyanomethyl)-N-ethylpyridine-2-carboxamide
  • 2-[(Heptan-4-yl)amino]-N,N-dimethylacetamide
  • 2-(4-Fluorophenyl)thiazole-5-carboxylic acid
  • 2-Cyclohexylthiazole-5-carboxylic acid
  • 2-(2,6-Difluorophenyl)-1,3-thiazole-5-carboxylic acid
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