MM 47755

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Names

[ CAS No. ]:
117620-87-8

[ Name ]:
MM 47755

[Synonym ]:
6-Deoxy-8-O-methylrabelomycin

Chemical & Physical Properties

[ Density]:
1.39g/cm3

[ Boiling Point ]:
583.3ºC at 760mmHg

[ Molecular Formula ]:
C20H16O5

[ Molecular Weight ]:
336.33800

[ Flash Point ]:
214.3ºC

[ Exact Mass ]:
336.10000

[ PSA ]:
80.67000

[ LogP ]:
2.35050

[ Vapour Pressure ]:
1.89E-14mmHg at 25°C

[ Index of Refraction ]:
1.652

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H410

[ Precautionary Statements ]:
P273-P501

[ RIDADR ]:
UN 3077 9 / PGIII

Articles

Angucyclinone antibiotics: total syntheses of YM-181741, (+)-ochromycinone, (+)-rubiginone B2, (-)-tetrangomycin, and MM-47755.

J. Org. Chem. 72(16) , 6116-26, (2007)

A concise and highly enantioselective route has been developed for the synthesis of angucyclinone-type natural products. Utilizing this strategy, total syntheses of five natural products YM-181741, (+...

Total synthesis of (-)-8-O-methyltetrangomycin (MM 47755).

Org. Lett. 8(12) , 2507-10, (2006)

A stereoselective total synthesis of the natural antibiotic (-)-8-O-methyltetrangomycin 1 is reported. The essential steps for this convergent synthesis are the transformation of a geraniol epoxide in...

The cobalt way to angucyclinones: asymmetric total synthesis of the antibiotics (+)-rubiginone B2, (-)-tetrangomycin, and (-)-8-O-methyltetrangomycin.

Chemistry 16(29) , 8805-21, (2010)

A cobalt(I)-mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring ang...


More Articles


Related Compounds

  • MM 11253
  • MM-102
  • MM-102 TFA
  • MM 54
  • (5Z)-5-[(3aS,4S,5R,6aS)-4-(2-cyclohexylethynyl)-5-hydroxy-3,3a,4,5,6,6a-hexahydro-1H-pentalen-2-ylidene]pentanoic acid
  • MM-401
  • {[(1-Bromo-2-methylpropan-2-yl)oxy]methyl}cyclohexane
  • {[(1,4-Dichloro-3-iodobutan-2-yl)oxy]methyl}cyclohexane
  • {[(1-Chloro-3-iodo-2-methylpropan-2-yl)oxy]methyl}cyclohexane
  • 4-(Cyclohexylmethoxy)-4-(iodomethyl)oxane
  • ({[1-(Iodomethyl)cyclopentyl]oxy}methyl)cyclohexane
  • {[(1-Iodo-2-methylpropan-2-yl)oxy]methyl}cyclohexane
  • {[(1-Bromo-3-chloro-2-methylpropan-2-yl)oxy]methyl}cyclohexane
  • tert-butyl N-[2-(cyclohexylmethoxy)-3-iodo-2-methylpropyl]carbamate
  • 3-Bromo-4-(cyclohexylmethoxy)oxolane
  • {[(3-Bromo-1,4-dichlorobutan-2-yl)oxy]methyl}cyclohexane
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