4-Methoxy-3-nitrotoluene

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Names

[ CAS No. ]:
119-10-8

[ Name ]:
4-Methoxy-3-nitrotoluene

[Synonym ]:
4-Methoxy-3-nitrotoluene
EINECS 204-296-4
BENZENE,1-METHOXY-4-METHYL-2-NITRO-
1-Methoxy-4-methyl-2-nitrobenzene
WNR C1 FO1
Methyl 4-methyl-2-nitrophenyl ether
Anisole, 4-methyl-2-nitro-
MFCD00024540
BENZENE,1-METHOXY-4-METHYL-2-NITRO
Benzene, 1-methoxy-4-methyl-2-nitro-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
289.4±0.0 °C at 760 mmHg

[ Melting Point ]:
8-9 °C(lit.)

[ Molecular Formula ]:
C8H9NO3

[ Molecular Weight ]:
167.162

[ Flash Point ]:
136.1±23.8 °C

[ Exact Mass ]:
167.058243

[ PSA ]:
55.05000

[ LogP ]:
2.19

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.538

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Methyl-2-nitrophenol
  • Dimethyl sulfate
  • 4-Methylanisole
  • methyl iodide
  • Isopropanol
  • tetranitromethane
  • Methanol
  • 1-Chloro-4-methyl-2-nitrobenzene
  • p-Cresol
  • 4-Chlorotoluene

DownStream

  • 4-Methoxy-3-Nitrobenzylthioacetic Acid
  • [(4-Methoxy-3-nitrobenzyl)sulfonyl]acetic acid
  • Para-Cresidine
  • 4-Chloro-2-methoxy-5-methylaniline
  • 4-Methoxy-3-nitrobenzylbromide
  • bis(2-methoxy-5-methyl-phenyl)diazene
  • 5,5'-dimethoxy-2,2'-dimethyl-benzidine
  • 4-Methyl-2-nitrophenol
  • 2,6-Dinitro-4-methyl anisole
  • (Z)-3-methoxy-6-methyl-4,6-dinitrocyclohexa-2,4-dienyl acetate

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

1-Dibromo-methyl-4-meth-oxy-2-nitro-benzene.

Acta Crystallogr. Sect. E Struct. Rep. Online 65(9) , o2193-94, (2009)

The asymmetric unit of the title compound, C(8)H(7)Br(2)NO(3), comprises two crystallographically independent mol-ecules (A and B). The nitro groups are twisted from the attached benzene rings, making...

Theoretical calculations of chemical interactions. Part 4. Aromatic nucleophilic substitutions and SN 2 reactions of 4-and 6-substituted 2-nitroanisoles. Nudelman NS and Palleros DR.

J. Chem. Soc., Perkin Trans. II 6 , 805-9, (1985)


More Articles

Related Compounds

  • 4-methoxy-3-phenylmethoxybenzoyl chloride
  • 4-methoxy-3-[5-(trifluoromethyl)tetrazol-1-yl]benzaldehyde
  • 4-methoxy-3-methylsulfanylquinoline
  • 4-Methoxy-3-(2-naphthyl)phthalide
  • 4-METHOXY-3-NITROBENZONITRILE
  • 4-methoxy-3-(1-naphthyl)phthalide