2-Nitrodiphenylamine

Names

[ CAS No. ]:
119-75-5

[ Name ]:
2-Nitrodiphenylamine

[Synonym ]:
EINECS 204-348-6
2-NITRO-N-PHENYLBENZENAMINE
MFCD00007089
Benzenamine, 2-nitro-N-phenyl-
2-Nitrodiphenylamine
2-Nitro-phenyl)-phenyl-amine
2-Nitro-N-phenylaniline

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
353.7±25.0 °C at 760 mmHg

[ Melting Point ]:
74-76 °C(lit.)

[ Molecular Formula ]:
C₁₂H₁₀N₂O₂

[ Molecular Weight ]:
214.220

[ Flash Point ]:
167.7±23.2 °C

[ Exact Mass ]:
214.074234

[ PSA ]:
57.85000

[ LogP ]:
3.40

[ Vapour density ]:
10.7 (vs air)

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.666

[ Water Solubility ]:
negligible

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29214400

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Bromobenzene
2-Nitroaniline
Iodobenzene
1-Bromo-2-nitrobenzene
2-nitrophenyl nonaflate
1-Iodo-2-nitrobenzene
2-Nitrochlorobenzene
Chlorobenzene
2-Iodocyclohex-2-en-1-one

DownStream

N-Nitroso-N-phenyl-2-nitroaniline
1-Phenyl-1H-benzimidazole
Phenazine
1,2-Diphenylbenzimidazole
9-Ethyl-9H-carbazole
N1-Phenylbenzene-1,2-diamine
1-Nitro-9H-carbazole
9-Methylcarbazole
Acetamide,N-(2-nitrophenyl)-N-phenyl-
N-(4-Chlorophenyl)-2-nitroaniline

Customs

[ HS Code ]: 2921440000

[ Summary ]:
2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Interfacial solubilization of model amphiphilic molecules in block copolymer micelles.

J. Am. Chem. Soc. 125(39) , 11993-2000, (2003)

We investigate the solubilization of 2-nitrodiphenylamine, a hydrophobic but polar dye molecule, in aqueous solutions of polystyrene(310)-b-poly(acrylic acid)(47) micelles. The solubilization capacity...

Fabrication and characterisation of 2NDPA-loaded poly(lactide-co-glycolide) (PLG) microspheres for explosive safety.

J. Microencapsul. 29(6) , 569-75, (2012)

We demonstrate the microencapsulation of a double-base (DB) rocket propellant stabiliser, 2-nitrodiphenylamine (2-NDPA), that can potentially increase the shelf life of DB rocket propellants. Poly(lac...

Degradation of 2-nitrodiphenylamine, a component of Otto Fuel II, by Clostridium spp.

Anaerobe 4(2) , 95-102, (1998)

Otto Fuel II, a propellant in torpedoes, is composed of 76% 1,2 propanediol dinitrate (PGDN), 22.5% di-n-butyl sebacate, and 1.5% 2-nitrodiphenylamine (NDPA), and is largely recalcitrant to aerobic mi...