L-Lysine, N6-formyl-

Names

[ Name ]:
L-Lysine, N6-formyl-

[Synonym ]:
Nepsilon-ForMyl-L-lysine
N(6)-formyl-L-lysine
MFCD00037362
N-ε-FORMYL-L-LYSINE
H-Lys(For)-OH
Nε-Formyl-L-lysine
N-EPSILON-FORMYL-L-LYSINE

Chemical & Physical Properties

[ Density]:
1.169g/cm3

[ Boiling Point ]:
438.5ºC at 760mmHg

[ Molecular Formula ]:
C₇H₁₄N₂O₃

[ Molecular Weight ]:
174.19800

[ Flash Point ]:
219ºC

[ Exact Mass ]:
174.10000

[ PSA ]:
92.42000

[ LogP ]:
1.04170

[ Vapour Pressure ]:
6.46E-09mmHg at 25°C

[ Index of Refraction ]:
3 ° (C=0.9, H2O)

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2924199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

L-Lysine
1,1-Diethyl-3-formyl-3-methoxyurea
Ethyl formate
N-Boc-N'-formyl-L-lysine
L-(+)-Lysine monohydrochloride
N-Boc-L-lysine
For-DL-Lys(-For)-OH
DL-Lysine monohydrochloride

DownStream

L(-)-Pipecolinic acid
N-Boc-N'-formyl-L-lysine

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Analysis of glycated and ascorbylated proteins by gas chromatography-mass spectrometry.

J. Agric. Food Chem. 50 , 5697-5703, (2002)

Proteins or poly-L-lysine which were incubated in the presence of ascorbic acid, dehydroascorbic acid (ascorbylation), or various sugars (glycation) were analyzed by gas chromatography-mass spectromet...

The isolation of Nepsilon-formyl-L-lysine from the reaction between formaldehyde and L-lysine and its identification by OPLC and NMR spectroscopy.

J. Pharm. Biomed. Anal. 3 , 343-349, (1985)

From the reaction between l-lysine and formaldehyde, Nepsilon-formyl-L-lysine was isolated by means of ion-exchange column chromatography. The identification of Nepsilon-formyl-L-lysine was carried ou...

Quantitative analysis of histone modifications: formaldehyde is a source of pathological n(6)-formyllysine that is refractory to histone deacetylases.

PLoS Genet. 9(2) , e1003328, (2013)

Aberrant protein modifications play an important role in the pathophysiology of many human diseases, in terms of both dysfunction of physiological modifications and the formation of pathological modif...

L-Lysine,N6-(1-oxotetradecyl)-N2-[(phenylmethoxy)carbonyl]-
L-Lysine,N6,N6'-(1,10-dioxo-1,10-decanediyl)bis- (9CI)
L-Lysine,N6-(triphenylmethyl)-
L-Lysine,N6-[(2-hydroxyphenyl)methylene]-
L-Lysine,N6-[(3-methoxypropoxy)carbonyl]-
L-Lysine, N6-acetyl-N2,N6-bis[1-[[(1,1-dimethylethyl)amino]carbonyl]-2-methylpropyl]-, methyl ester (9CI)
1-[2-(Tert-butoxy)-2-oxoethyl]-5-(5-fluoro-2-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxylic acid
1-[2-(Tert-butoxy)-2-oxoethyl]-5-(2-fluoro-6-methoxyphenyl)-2-oxo-1,2-dihydropyridine-3-carboxylic acid
1-[2-(Tert-butoxy)-2-oxoethyl]-5-(2-chloro-6-fluorophenyl)-2-oxo-1,2-dihydropyridine-3-carboxylic acid
1-[2-(Tert-butoxy)-2-oxoethyl]-5-(5-chloro-2-fluorophenyl)-2-oxo-1,2-dihydropyridine-3-carboxylic acid
2-(1-methyl-1H-imidazol-2-yl)oxolane-2-carboxylic acid
[4-(2-Fluorophenyl)oxolan-2-yl]methanesulfonyl chloride
[4-(3-Methoxyphenyl)oxolan-2-yl]methanesulfonyl chloride
[4-(4-Nitrophenyl)oxolan-2-yl]methanesulfonyl chloride
[4-(2-Methoxyphenyl)oxolan-2-yl]methanesulfonyl chloride
[4-(3-Fluorophenyl)oxolan-2-yl]methanesulfonyl chloride

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