dibutylmagnesium

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Names

[ CAS No. ]:
1191-47-5

[ Name ]:
dibutylmagnesium

[Synonym ]:
EINECS 214-736-7
MFCD00015225
Di-N-butylmagnesium

Chemical & Physical Properties

[ Density]:
0.749 g/mL at 20 °C

[ Melting Point ]:
-71ºC

[ Molecular Formula ]:
C8H18Mg

[ Molecular Weight ]:
138.53400

[ Flash Point ]:
21 °F

[ Exact Mass ]:
138.12600

[ LogP ]:
3.50820

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H250-H260-H302-H304-H314-H336-H361f-H373-H412

[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P301 + P310-P302 + P334-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P331-P370 + P378-P403 + P235-P422

[ Hazard Codes ]:
F+,C,T,F,N

[ Risk Phrases ]:
R12

[ Safety Phrases ]:
16-26-36/37/39-43-45-7/8-62-61-60

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromobutane
  • 1-Butene
  • Butyl iodide
  • SULFURIC ACID, DIBUTYL ESTER
  • n-Butyllithium
  • Butylmagnesium chloride
  • 1-Chlorobutane
  • Butylmagnesium Bromide
  • dibutylmercury
  • Diethyl ether

DownStream

  • Fenipentol
  • 2,4-Bis(trifluoromethyl)benzoic acid
  • Methylbenzylalcohol
  • 3-hydroxy-1,3-diphenylbutan-1-one
  • 2-phenylhexan-2-ol
  • Hept-1-ene
  • 2-Hexanol
  • 1-Hexanol
  • n-butylamine
  • Magnesium choride

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Some novelties in olefin carbometallation assisted by alkyl-magnesium and-aluminium derivatives and catalyzed by zirconium and titanium complexes. Dzhemilev UM and Vostrikova OS

J. Organomet. Chem. 285(1) , 43-51, (1985)

Multivalent cation intercalation Bruce PG, et al.

Solid State Ionics 53-56(1) , 351-355, (1992)

Chemical and physical evidence for metal–metal interchange between lithium alkoxides and di-n-butylmagnesium. Micha Screttas M, et al.

Tetrahedron Lett. 43(27) , 4871-4873, (2002)


More Articles

Related Compounds

  • Dibutylmagnesium
  • dibutyl diethylphosphoramidite
  • dibutyl(hex-1-en-2-yl)borane
  • dibutyl (1-chloroethylideneamino) phosphate
  • [dibutyl-(4-chlorobenzoyl)oxystannyl] 4-chlorobenzoate
  • dibutyl 1H-pyrrole-3,4-dicarboxylate
  • (dibutyl phosphorous) dimethylphosphinic anhydride
  • N-(5-Hydroxy-2-methoxyphenyl)methanesulfonamide
  • 6-methoxy-1'-(3-methylbutyl)-2,3,4,9-tetrahydrospiro[beta-carboline-1,3'-indol]-2'(1'H)-one
  • 3-Acetyloxirane-2-carboxylic acid
  • N-2-benzothiazolyl-3-nitrobenzenesulfonamide
  • N-(4,5-dimethyl-2-thiazolyl)-3-nitrobenzenesulfonamide
  • 3-fluoro-N-[(2E)-5-(tetrahydrofuran-2-yl)-1,3,4-thiadiazol-2(3H)-ylidene]benzamide
  • (1R)-3-Chloro-1-(2-thienyl)propyl butanoate
  • 5-Methyl-2,7-naphthyridine-4-carboxaldehyde
  • 2-(Pyridin-2-yl)acetyl chloride hydrochloride
  • 2-(5-Nitro-1,3-dioxoisoindol-2-yl)propanoic acid
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