dibutylmagnesium

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Names

[ CAS No. ]:
1191-47-5

[ Name ]:
dibutylmagnesium

[Synonym ]:
EINECS 214-736-7
MFCD00015225
Di-N-butylmagnesium

Chemical & Physical Properties

[ Density]:
0.749 g/mL at 20 °C

[ Melting Point ]:
-71ºC

[ Molecular Formula ]:
C8H18Mg

[ Molecular Weight ]:
138.53400

[ Flash Point ]:
21 °F

[ Exact Mass ]:
138.12600

[ LogP ]:
3.50820

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H250-H260-H302-H304-H314-H336-H361f-H373-H412

[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P301 + P310-P302 + P334-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P331-P370 + P378-P403 + P235-P422

[ Hazard Codes ]:
F+,C,T,F,N

[ Risk Phrases ]:
R12

[ Safety Phrases ]:
16-26-36/37/39-43-45-7/8-62-61-60

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromobutane
  • 1-Butene
  • Butyl iodide
  • SULFURIC ACID, DIBUTYL ESTER
  • n-Butyllithium
  • Butylmagnesium chloride
  • 1-Chlorobutane
  • Butylmagnesium Bromide
  • dibutylmercury
  • Diethyl ether

DownStream

  • Fenipentol
  • 2,4-Bis(trifluoromethyl)benzoic acid
  • Methylbenzylalcohol
  • 3-hydroxy-1,3-diphenylbutan-1-one
  • 2-phenylhexan-2-ol
  • Hept-1-ene
  • 2-Hexanol
  • 1-Hexanol
  • n-butylamine
  • Magnesium choride

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Some novelties in olefin carbometallation assisted by alkyl-magnesium and-aluminium derivatives and catalyzed by zirconium and titanium complexes. Dzhemilev UM and Vostrikova OS

J. Organomet. Chem. 285(1) , 43-51, (1985)

Multivalent cation intercalation Bruce PG, et al.

Solid State Ionics 53-56(1) , 351-355, (1992)

Chemical and physical evidence for metal–metal interchange between lithium alkoxides and di-n-butylmagnesium. Micha Screttas M, et al.

Tetrahedron Lett. 43(27) , 4871-4873, (2002)


More Articles

Related Compounds

  • Dibutylmagnesium
  • dibutyl diethylphosphoramidite
  • dibutyl(hex-1-en-2-yl)borane
  • dibutyl (1-chloroethylideneamino) phosphate
  • [dibutyl-(4-chlorobenzoyl)oxystannyl] 4-chlorobenzoate
  • dibutyl 1H-pyrrole-3,4-dicarboxylate
  • (dibutyl phosphorous) dimethylphosphinic anhydride
  • 9-ethyl-N-[(4-fluorophenyl)methyl]-9H-purin-6-amine
  • 1-(2-Cyclopropyl-6-methylpyrimidin-4-yl)-4-phenylpiperidine-4-carbonitrile
  • 3-[4-(3-Cyclopropyl-1,2,4-thiadiazol-5-yl)piperazin-1-yl]-6-(2,4-dimethyl-1,3-thiazol-5-yl)pyridazine
  • 1-(6-Cyclobutylpyrimidin-4-yl)-4-phenylpiperidine-4-carbonitrile
  • 9-ethyl-6-{4-[3-(trifluoromethyl)phenyl]piperazin-1-yl}-9H-purine
  • 1-[(2-Cyclopropyl-1,3-thiazol-4-yl)methyl]-4-phenylpiperidine-4-carbonitrile
  • N-tert-butyl-2-[4-(6-fluoro-1,2-benzoxazol-3-yl)piperidin-1-yl]acetamide
  • 6-(4-{5H,6H,7H-cyclopenta[d]pyrimidin-4-yl}piperazin-1-yl)-9-(2-methoxyethyl)-9H-purine
  • 2-[4-(Furan-2-carbonyl)piperazin-1-yl]-4,6-dimethoxypyrimidine
  • 5-(5-{3-Ethyl-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}-octahydropyrrolo[3,4-c]pyrrol-2-yl)-3-(methoxymethyl)-1,2,4-thiadiazole
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