Snyder bromination reagent

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Names

[ CAS No. ]:
1198402-81-1

[ Name ]:
Snyder bromination reagent

[Synonym ]:
BROMODIETHYLSULFONIUM BROMOPENTACHLOROANTIMONATE(V)

Chemical & Physical Properties

[ Molecular Formula ]:
C4H10Br2Cl5SSb

[ Molecular Weight ]:
549.020

[ Exact Mass ]:
543.635071

[ Storage condition ]:
?20°C

Safety Information

[ Symbol ]:

GHS03, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H272-H302 + H332-H314

[ Precautionary Statements ]:
P220-P280-P305 + P351 + P338-P310

[ Hazard Codes ]:
C,Xn,N

[ Risk Phrases ]:
20/22-34-51/53

[ Safety Phrases ]:
26-36/37/39-45-61

[ RIDADR ]:
UN 3084 5.1(8) / PGII

Articles

Et2SBrSbCl5Br: an effective reagent for direct bromonium-induced polyene cyclizations.

Angew. Chem. Int. Ed. Engl. 48 , 7899-7903, (2009)

Simple reagents for direct halonium-induced polyene cyclizations.

J. Am. Chem. Soc. 132 , 14303-14314, (2010)

Although there are many reagent combinations that can initiate polyene cyclizations, simple electrophilic halogen sources have not yet proven broadly effective as promoters of such processes. Herein i...


More Articles

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