O-ACETOTOLUIDIDE

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Names

[ CAS No. ]:
120-66-1

[ Name ]:
O-ACETOTOLUIDIDE

[Synonym ]:
2'-Methylacetanilide
EINECS 204-414-4
N-(o-Tolyl)acetamide
N-Acetyl-o-toluidine
O-ACETOTOLUIDIDE
2-METHYLACETANILIDE
N-(2-methylphenyl)acetamide
o-Acetotoluidine
MFCD00014961

Chemical & Physical Properties

[ Density]:
1.16

[ Boiling Point ]:
296 °C

[ Melting Point ]:
109-112 °C

[ Molecular Formula ]:
C9H11NO

[ Molecular Weight ]:
149.19000

[ Flash Point ]:
296°C

[ Exact Mass ]:
149.08400

[ PSA ]:
29.10000

[ LogP ]:
2.02640

[ Vapour Pressure ]:
0.001mmHg at 25°C

[ Index of Refraction ]:
1.567

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AN2900000
CHEMICAL NAME :
o-Acetotoluidide
CAS REGISTRY NUMBER :
120-66-1
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C9-H11-N-O
MOLECULAR WEIGHT :
149.21
WISWESSER LINE NOTATION :
1VMR B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1450 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
47 nmol/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 137,39,1984

Safety Information

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26-S36

[ RTECS ]:
AN2900000

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Acetyl chloride
  • o-Toluidine
  • Acetamide
  • 4-Iodotoluene
  • Ethanoic anhydride
  • 2-Chlorotoluene
  • acetic acid
  • Ethanol
  • Acetonitrile
  • E-ortho-methylacetophenone oxime

DownStream

  • 2-CHLORO-3-NITROTOLUENE
  • 2-Methyl-5-nitrophenol
  • 2-Bromo-3-nitrotoluene
  • 5-Bromoindazole
  • 4-Chloro-2-methylbenzonitrile
  • Acetamide,N-(2-methyl-6-nitrophenyl)-
  • Acetamide,N-(2-methyl-4-nitrophenyl)-
  • Acetamide,N-(2-methyl-5-nitrophenyl)-
  • n,n-diethyl-o-toluidine
  • 2-Ethylaminotoluene

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • o-ACETOTOLUIDIDE,2-IODO
  • 2-BROMO-O-ACETOTOLUIDIDE
  • o-Acetotoluidide,N-methyl
  • o-Acetotoluidide,4'-nitro
  • α-Chloro-o-acetotoluidide
  • 6'-nitro-o-acetotoluidide
  • 3-(4-acetamidophenyl)-1-methyl-1H-pyrazole-4-carboxylic acid
  • tert-butyl N-(6-cyano-1,3-benzoxazol-2-yl)carbamate
  • tert-butyl N-(2-cyanoethyl)-N-(4-fluorophenyl)carbamate
  • tert-butyl N-[3-(2-methylpropanoyl)pyridin-4-yl]carbamate
  • 5-[Butyl(methyl)amino]-2-acetamidobenzoic acid
  • 1-[5-(2-fluorophenyl)-1-methyl-2-oxo-2,3-dihydro-1H-1,4-benzodiazepin-3-yl]-3-[(1-methyl-1H-pyrazol-4-yl)methyl]urea
  • rac-benzyl (3R,4S)-3-(dimethylamino)-4-hydroxypyrrolidine-1-carboxylate
  • Ammonium bis(5,5,6,6,7,7,8,8,8-nonafluoro-1-octyl) phosphate
  • Tert-butyl 1'-cyano-4'-methyl-3'-oxaspiro[azetidine-3,2'-bicyclo[2.1.1]hexane]-1-carboxylate
  • rac-benzyl N-[(3R,4R)-4-hydroxy-1-methylpyrrolidin-3-yl]-N-methylcarbamate