2-Phenylbenzaldehyde

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Names

[ Name ]:
2-Phenylbenzaldehyde

[Synonym ]:
[1,1'-Biphenyl]-2-carboxaldehyde
Biphenyl-2-carbaldehyde
Biphenyl-2-carboxaldehyde
2-Biphenylcarbaldehyde
2-Phenylbenzaldehyde
2-Biphenylcarboxaldehyde
(1,1'-Biphenyl)-2-carboxaldehyde
VHR BR
MFCD01740431

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
332.4±21.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₃H₁₀O

[ Molecular Weight ]:
182.218

[ Flash Point ]:
193.2±8.3 °C

[ Exact Mass ]:
182.073166

[ PSA ]:
17.07000

[ LogP ]:
3.10

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.609

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DV1771000

CHEMICAL NAME :: (1,1'-Biphenyl)-2-carboxaldehyde

CAS REGISTRY NUMBER :: 1203-68-5

BEILSTEIN REFERENCE NO. :: 2081880

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C13-H10-O

MOLECULAR WEIGHT :: 182.23

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >1500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FRPSAX Farmaco, Edizione Scientifica. (Casella Postale 227, 27100 Pavia, Italy) V.8-43 1953-88 For publisher information, see FRMCE8 Volume(issue)/page/year: 19,964,1964

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DV1771000

[ HS Code ]:
2912299000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Benzhydrol
2-Chlorobenzaldehyde
Phenylboronic acid
2-Bromobenzaldehyde
Phenyltrimethoxysilane
2-Methyl Biphenyl
Tri-n-butylphenyltin
2-Bromobiphenyl
N,N-Dimethylformamide
Phenyltriethoxysilane

DownStream

Biphenyl-2-carboxylic acid
3-(2-phenylphenyl)propanoic acid
2-Methyl Biphenyl
9H FLUORENE
Phenanthridine
9-Fluorene acetic acid
N-benzyl-2-phenylbenzamide
[1,1'-biphenyl]-2-carbonitrile
Benzhydrol
4-Biphenylmethylamine

Customs

[ HS Code ]: 2912299000

[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Microbial formation and degradation of oxygen-containing polycyclic aromatic hydrocarbons (OPAHs) in soil during short-term incubation. Wilcke W, et al.

Environ. Pollut. 184 , 385-390, (2014)

Synthesis and application of ortho-palladated complex of (4-phenylbenzoylmethylene) triphenylphosphorane as a highly active catalyst in the Suzuki cross-coupling reaction. Karami K, e tal.

J. Organomet. Chem. 696(4) , 940-945, (2011)

The preparation of 9-alkylthiofluorenes from biphenyl-2-carboxaldehydes. Leber JD and Elliott JD.

Tetrahedron Lett. 30(49) , 6849-6850, (1989)